A New Diiminopyridyl Cobalt Complex [CoCl2L] (L = 2,6-Bis(N,N’bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine)

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	A New Diiminopyridyl Cobalt Complex [CoCl2L] (L = 2,6-Bis(N,N’bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine)
	Xia YN(夏娅娜)
刊名	Chinese J. Struct. Chem.
	2010
卷号	29 期号:6 页码:869-874
关键词	2,6-bis(N,N΄-bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino)) pyridine cobalt crystal structure fluorescence
ISSN号	0254-5861
通讯作者	吴彪
中文摘要	The reaction of CoCl2·6H2O with 2,6-bis(N,N΄-bis(2,6-diisopropyl-4-(2,3-dimethyoxyl-benzoylamide)phenylimino))pyridine (L) afforded the complex [CoCl2L], which was fully characterized by elemental analysis, UV-vis, IR spectroscopy, fluorescence, and X-ray diffraction analysis. The compound is of triclinic system, space group P1 with a = 13.058(3), b = 13.798(3), c =16.695(3) Å, α = 98.191(3), β = 102.792(3), γ = 101.820(3)°, V = 2815.0(9) Å3, Z = 2, F(000) = 1122, μ = 0.45 mm−1, R = 0.061 and wR = 0.1349 for 9842 observed reflections (I > 2σ(I)). The Co(II) center adopts a distorted square-pyramidal coordination geometry. The extended structure shows a one-dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions.
学科主题	金属有机功能材料
收录类别	SCI
资助信息	the National Natural Science Foundation of China (No. 20872149)
语种	英语
公开日期	2012-11-30
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/2286]
专题	兰州化学物理研究所_OSSO国家重点实验室
推荐引用方式 GB/T 7714	Xia YN. A New Diiminopyridyl Cobalt Complex [CoCl2L] (L = 2,6-Bis(N,N’bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine)[J]. Chinese J. Struct. Chem.,2010,29(6):869-874.
APA	夏娅娜.(2010).A New Diiminopyridyl Cobalt Complex [CoCl2L] (L = 2,6-Bis(N,N’bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine).Chinese J. Struct. Chem.,29(6),869-874.
MLA	夏娅娜."A New Diiminopyridyl Cobalt Complex [CoCl2L] (L = 2,6-Bis(N,N’bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide)phenylimino))pyridine)".Chinese J. Struct. Chem. 29.6(2010):869-874.