Sulfate binding in zinc(II) complexes of a monopyridylurea ligand N-(1-naphthyl)-N′-(3-pyridyl)urea

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	Sulfate binding in zinc(II) complexes of a monopyridylurea ligand N-(1-naphthyl)-N′-(3-pyridyl)urea
	Huang XJ(黄晓卷); Xia YN(夏娅娜); Yang XJ(杨晓娟)
刊名	Inorg. Chem. Commun.
	2010
卷号	13 页码:1103-1107
关键词	Sulfate binding N-(1-naphthyl)-N′-(3-pyridyl)urea Hydrogen-bonded frameworks Fluorescence
ISSN号	1387-7003
通讯作者	吴彪
中文摘要	Two zinc(II) complexes of a urea-functionalized pyridyl ligand, [Zn(SO4)L3]·CH3OH (1) and {[Zn(μ2-SO4)L2]·0.5CH3OH}n (2) (L=N-(1-naphthyl)-N′-(3-pyridyl)urea), have been synthesized by the reaction of L with ZnSO4·7H2O under different conditions. Complex 1 is a hydrogen-bonded 2D grid structure in which the sulfate anion not only coordinates to the ZnII ion as a monodentate ligand but also forms multiple hydrogen bonds with the urea groups of adjacent molecules. In complex 2 the sulfate ion serves as a μ2-bridging ligand, connecting the ZnII ions to form an infinite 1D organic–inorganic hybrid framework. Meanwhile, the sulfate anion is also bound by neighboring ligands through hydrogen bonds between urea groups and the noncoordinated oxygen atoms. The solid-state emission spectra of 1 and 2 show a red shift of the fluorescence emission of ligand L.
学科主题	金属有机功能材料
收录类别	SCI
资助信息	the National Natural Science Foundation of China (Grant No. 20872149);the “Bairen Jihua” project of the Chinese Academy of Sciences
语种	英语
公开日期	2012-11-30
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/2284]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_ERC国家工程研究中心
推荐引用方式 GB/T 7714	Huang XJ,Xia YN,Yang XJ. Sulfate binding in zinc(II) complexes of a monopyridylurea ligand N-(1-naphthyl)-N′-(3-pyridyl)urea[J]. Inorg. Chem. Commun.,2010,13:1103-1107.
APA	黄晓卷,夏娅娜,&杨晓娟.(2010).Sulfate binding in zinc(II) complexes of a monopyridylurea ligand N-(1-naphthyl)-N′-(3-pyridyl)urea.Inorg. Chem. Commun.,13,1103-1107.
MLA	黄晓卷,et al."Sulfate binding in zinc(II) complexes of a monopyridylurea ligand N-(1-naphthyl)-N′-(3-pyridyl)urea".Inorg. Chem. Commun. 13(2010):1103-1107.