Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions

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	Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions
	Sun KP(孙鲲鹏)
刊名	Catalysis Communications
	2008
卷号	9 页码:386-390
关键词	Alcohols Aldehydes Hydrogen peroxide Oxidation Palladium Sodium oxalate
ISSN号	1566-7367
通讯作者	徐贤伦
中文摘要	With oxygen that was supplied by hydrogen peroxide as oxidant, secondary and primary aliphatic alcohols, primary allylic alcohols could be efficiently oxidized to aldehydes or ketones in high yields in the presence of Pd (OAc)2 sodium oxalate (SO) under solvent-free conditions, it is a high yielding and operationally simple method. Acetic acid is testified to attend the reaction, the acetate ligands are environed to serve two purposes: as a ligand for the PdII center and as a base to deprotonate the Pd-bound alcohol, but acetic acid has not shown in previous bidentate ligands systems, so a mechanism is proposed on the basis of the mechanisms reported by the pioneers.
学科主题	物理化学
收录类别	SCI
语种	英语
公开日期	2012-11-09
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/1986]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_绿色化学研究发展中心
推荐引用方式 GB/T 7714	Sun KP. Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions[J]. Catalysis Communications,2008,9:386-390.
APA	孙鲲鹏.(2008).Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions.Catalysis Communications,9,386-390.
MLA	孙鲲鹏."Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions".Catalysis Communications 9(2008):386-390.