Coordination Networks from Zero-Dimensional Metallomacrocycle, One-Dimensional Chain to Two-Dimensional Sheet Based on a Ditopic Diiminopyridine Ligand and Group 12 Metals

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	Coordination Networks from Zero-Dimensional Metallomacrocycle, One-Dimensional Chain to Two-Dimensional Sheet Based on a Ditopic Diiminopyridine Ligand and Group 12 Metals
	Yang XJ(杨晓娟); Yang XJ(杨晓娟)
刊名	Crystal Growth & Design
	2010
卷号	10 期号:5 页码:2331-2341
ISSN号	1528-7505
通讯作者	吴彪 ; 唐宁 ; 杨晓娟
中文摘要	The reaction of a ditopic diiminopyridine ligand 2,6-bis(1-(2,6-diisopropyl-4-(pyridin-3-yl)phenylimino)ethyl)-pyridine (L) with group 12 metal salts in various solvent systems afforded 12 metal-organic coordination complexes, including zero-dimensional (0D) metallomacrocycle, one-dimensional (1D) chain, and two-dimensional (2D) network structures: [Zn4Cl8L2] 3 2C7H8 3 2CH3COCH3 3 3H2O (1a), {[Zn2Cl4L] 3 2CH3OH3 2CHCl3 3 2H2O}n (1b), {[ZnCl2L] 3 0.5CH2Cl2 3 0.5H2O}n (1c), {[ZnBr2L] 3 CH2Cl2}n (2), [ZnI2L]n (3), {[Zn(NO3)2L2 3 2C7H8]}n (4), {[CdCl2L2] 3 2CH2Cl2}n (5), {[Cd(NO3)2L2] 3CH2Cl2}n (6), {[Cd(ClO4)2L2] 3 CH2Cl2}n (7), {[Hg4(μ2-L2)(μ2-Cl2)(μ-HgCl2)Cl6] 3 2H2O}n (8), {[HgBr2L] 3CH3CN3 0.5CH2Cl2}n (9), and {[HgI2L] 3 0.5CH2Cl2}n (10). In these complexes, the semirigid ligand L exhibits four kinds of coordination modes [(syn, syn, syn), (syn, syn, anti), (anti, anti, syn), (anti, anti, anti)], leading to the formation of various supramolecular structures. Complex 1a is a tetranuclear metallomacrocycle. 1b contains 1D zigzag chains propagating along two different directions, which further pack into a noninterpenetrated three-dimensional (3D) framework by hydrogen-bonding interactions.Complexes 1c, 2, 3, 9, and10 exhibit a1Dhelical chain structure, while 4, 5, 6, and7 are 1D looped-chain coordination polymers. Complex 8 displays an unprecedented pentanuclear Hg(II)-based 2D network with both HgCl2 andHg2Cl2 bridges. It is noteworthy that 1a and 1b are supramolecular isomers formed in different solvent systems.The effects of the solvent, metal center, and anion on the different conformations adopted by the ligand and the structure of the products have been discussed. Additionally, the luminescent properties of the complexes have been investigated in the solid state, which display increased ligand-based fluorescence emission at room temperature.
学科主题	金属有机功能材料
收录类别	SCI
资助信息	the “Bairen Jihua” project of the Chinese Academy of Sciences
语种	英语
WOS记录号	WOS:000277273900047
公开日期	2012-09-21
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/459]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_ERC国家工程研究中心
通讯作者	Yang XJ(杨晓娟); Yang XJ(杨晓娟)
推荐引用方式 GB/T 7714	Yang XJ,Yang XJ. Coordination Networks from Zero-Dimensional Metallomacrocycle, One-Dimensional Chain to Two-Dimensional Sheet Based on a Ditopic Diiminopyridine Ligand and Group 12 Metals[J]. Crystal Growth & Design,2010,10(5):2331-2341.
APA	杨晓娟,&杨晓娟.(2010).Coordination Networks from Zero-Dimensional Metallomacrocycle, One-Dimensional Chain to Two-Dimensional Sheet Based on a Ditopic Diiminopyridine Ligand and Group 12 Metals.Crystal Growth & Design,10(5),2331-2341.
MLA	杨晓娟,et al."Coordination Networks from Zero-Dimensional Metallomacrocycle, One-Dimensional Chain to Two-Dimensional Sheet Based on a Ditopic Diiminopyridine Ligand and Group 12 Metals".Crystal Growth & Design 10.5(2010):2331-2341.