Synthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains

	Synthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains
	Dong, Da-Peng 1; Liu, Lei 1; Sun, Zhen-Gang 1; Jiao, Cheng-Qi 1; Liu, Zhong-Min 2; Li, Chao 1; Zhu, Yan-Yu 1; Chen, Kai 1; Wang, Cheng-Lin 1
刊名	crystal growth & design
	2011-12-01
卷号	11 期号:12 页码:5346-5354
ISSN号	待补充
通讯作者	zhen-gangsun
产权排序	2,5
中文摘要	synthesis, crystal structures, and luminescence and magnetic properties of 3d chiral and achiral lanthanide diphosphonates containing left- and right-handed helical chains
英文摘要	using the heptadentate ligand hedph(4) (1-hydroxyethylidenediphosphonic acid) and lanthanide chloride, two isomorphous series of coordination frameworks of the general formula [nh4] [ln(hedp)(h2o)]center dot h2o (series 1, orthorhombic p2(1)2(1)2(1), ln = la (1), ce (2), pr (3), nd (4)) and [nh4] [ln(hedp)(h2o)] (series 2, orthorhombic pnma, ln = sm (5), eu (6), gd (7), tb (8), dy (9), y (10), er (11)) have been assembled and characterized with ir, elemental analysis, thermogravimetric analysis, and single-crystal and powder x-ray diffraction methods. in both series, each inorganic chain based on lno(8) and cpo3 polyhedra are interconnected through phosphonate ligands to form chiral and achiral 3d open-framework structures with left- and right-handed helical chains. meanwhile, the two series also exhibit two types of 3d framework structures with similar network topologies. the crystal water molecule plays an important role to induce chiral structure and affects the crystal packing of the molecules with extensive hydrogen bonding. the luminescence properties of compounds 5, 6, 8 and 9 and the magnetic property of compound 7 have also been studied.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, multidisciplinary ; crystallography ; materials science, multidisciplinary
研究领域[WOS]	chemistry ; crystallography ; materials science
关键词[WOS]	metal phosphonate chemistry ; carboxylate-phosphonates ; coordination polymers ; spontaneous resolution ; organic framework ; building-blocks ; porous solids ; zeolite-type ; series ; state
收录类别	SCI
语种	英语
WOS记录号	WOS:000297609100024
公开日期	2012-07-09
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/115851]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Liaoning Normal Univ, Sch Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Dong, Da-Peng,Liu, Lei,Sun, Zhen-Gang,et al. Synthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains[J]. crystal growth & design,2011,11(12):5346-5354.
APA	Dong, Da-Peng.,Liu, Lei.,Sun, Zhen-Gang.,Jiao, Cheng-Qi.,Liu, Zhong-Min.,...&Wang, Cheng-Lin.(2011).Synthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains.crystal growth & design,11(12),5346-5354.
MLA	Dong, Da-Peng,et al."Synthesis, Crystal Structures, and Luminescence and Magnetic Properties of 3D Chiral and Achiral Lanthanide Diphosphonates Containing Left- and Right-Handed Helical Chains".crystal growth & design 11.12(2011):5346-5354.