Exceptional thermal stability and thermodynamic properties of lithium based metal-organic framework

	Exceptional thermal stability and thermodynamic properties of lithium based metal-organic framework
	Jiang, Chun-Hong 1,3; Song, Li-Fang 1,3; Jiao, Cheng-Li 1,3; Zhang, Jian 1; Sun, Li-Xian 1; Xu, Fen 2; Du, Yong 4; Cao, Zhong 5
刊名	journal of thermal analysis and calorimetry
	2011
卷号	103 期号:1 页码:373-380
关键词	Lithium Molar heat capacity Metal-organic frameworks TG TMDSC
ISSN号	1388-6150
通讯作者	孙立贤
产权排序	1,1
中文摘要	exceptional thermal stability and thermodynamic properties of lithium based metal-organic framework
英文摘要	a three-dimensional lithium-based metal-organic framework li-2(2,6-ndc) ( 2,6-ndc = 2,6-naphthalene dicarboxylate) has been synthesized solvothermally and characterized by x-ray powder diffraction, elemental analysis, ft-ir spectroscopy, thermogravimetry and mass spectrometer analysis (tg-ms). the framework has exceptional stability and is stable to 863 k. the thermal decomposition characteristic of this compound was investigated through the tg-ms from 293 to 1250 k. the molar heat capacity of the compound was measured by temperature modulated differential scanning calorimetry (tmdsc) over the temperature range from 195 to 670 k for the first time. the thermodynamic parameters such as entropy and enthalpy versus 298.15 k based on the above molar heat capacity were calculated.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, analytical ; chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	heat-capacity ; coordination polymer ; photoluminescence ; separation ; catalysis ; mixtures ; pressure ; storage ; h-2 ; ch4
收录类别	SCI
语种	英语
WOS记录号	WOS:000287714400054
公开日期	2012-07-09
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/115779]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China 5.Changsha Univ Sci & Technol, Sch Chem & Environm Engn, Changsha 410076, Hunan, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Chun-Hong,Song, Li-Fang,Jiao, Cheng-Li,et al. Exceptional thermal stability and thermodynamic properties of lithium based metal-organic framework[J]. journal of thermal analysis and calorimetry,2011,103(1):373-380.
APA	Jiang, Chun-Hong.,Song, Li-Fang.,Jiao, Cheng-Li.,Zhang, Jian.,Sun, Li-Xian.,...&Cao, Zhong.(2011).Exceptional thermal stability and thermodynamic properties of lithium based metal-organic framework.journal of thermal analysis and calorimetry,103(1),373-380.
MLA	Jiang, Chun-Hong,et al."Exceptional thermal stability and thermodynamic properties of lithium based metal-organic framework".journal of thermal analysis and calorimetry 103.1(2011):373-380.