Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes

	Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes
	Zhao, Guang-Jiu 1; Yu, Fabiao 1; Zhang, Ming-Xing 1; Northrop, Brian H.2; Yang, Haibo 2; Han, Ke-Li 1; Stang, Peter J.2
刊名	journal of physical chemistry a
	2011-06-23
卷号	115 期号:24 页码:6390-6393
ISSN号	待补充
通讯作者	韩克利
产权排序	1,1
中文摘要	substituent effects on the intramolecular charge transfer and fluorescence of bimetallic platinum complexes
英文摘要	an investigation of a series of platinum-containing organometallic complexes for the study of fluorescence phenomena in organometallic chromophores controlled by the intrarnolecular charge transfer (ict) is presented in this work. we report steady-state and time-resolved spectroscopic experiments as well as quantum chemistry calculations to investigate the substituent effects on the ict and fluorescence emission. we demonstrate that the fluorescence maximum and lifetimes greatly depend on different substituents and the presence of bimetallic platinum donor. this work paves the way for an understanding of the fluorescence phenomena controlled by molecular ict characters of these kinds of platinum-containing organometallic complexes.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical ; physics, atomic, molecular & chemical
研究领域[WOS]	chemistry ; physics
关键词[WOS]	supramolecular rectangle ; terpyridyl complexes ; coordination cages ; dimer complex ; photochemistry ; symmetry ; systems ; intermediate ; spectroscopy ; photophysics
收录类别	SCI
语种	英语
WOS记录号	WOS:000291709400010
公开日期	2012-07-09
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/115233]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
推荐引用方式 GB/T 7714	Zhao, Guang-Jiu,Yu, Fabiao,Zhang, Ming-Xing,et al. Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes[J]. journal of physical chemistry a,2011,115(24):6390-6393.
APA	Zhao, Guang-Jiu.,Yu, Fabiao.,Zhang, Ming-Xing.,Northrop, Brian H..,Yang, Haibo.,...&Stang, Peter J..(2011).Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes.journal of physical chemistry a,115(24),6390-6393.
MLA	Zhao, Guang-Jiu,et al."Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes".journal of physical chemistry a 115.24(2011):6390-6393.