Tetracarboxylate-based Co(II), Ni(II) and Cu(II) three-dimensional coordination polymers: syntheses, structures and magnetic properties

	Tetracarboxylate-based Co(II), Ni(II) and Cu(II) three-dimensional coordination polymers: syntheses, structures and magnetic properties
	Su SQ ; Guo ZY ; Li GH ; Deng RP ; Song SY ; Qin C ; Pan CL ; Guo HD ; Cao F ; Wang S ; Zhang HJ
刊名	dalton transactions
	2010
卷号	39 期号:38 页码:9123-9130
关键词	METAL-ORGANIC FRAMEWORKS METHYLENEDIISOPHTHALIC ACID H4MDIP SELECTIVE GAS SORPTION BUILDING-BLOCKS CRYSTAL-STRUCTURES HYDROTHERMAL SYNTHESIS MOLECULAR-COMPLEXES FLUORITE TOPOLOGY COBALT COMPLEX COPPER(II)
ISSN号	1477-9226
通讯作者	zhang hj
中文摘要	methylenediisophthalic acid (h4mdip), as semi-rigid 'v'-shaped carboxylate ligands, react with coo, nio and cu(no3)(2)center dot 3h(2)o to give three novel coordination polymers [h3o](2)[co-3(mdip)(2)]center dot 2dmf (1), [ni-2(hmdip)(mu(2)-oh)(h2o)(3)(dmf)]center dot 4h(2)o center dot dmf (2) and [cu-3(mdip)(mu(2)-oh)(2)(h2o)(4)] center dot 6.5h(2)o (3) (dmf = n,n'-dimethylformamide). all compounds have been characterized by thermogravimetric analysis, ir spectroscopy, elemental and single-crystal x-ray diffraction analyses. complex 1 is an unusual open anionic framework that is defined as the metal-organic replica of fluorite. both 2 and 3 features a 3d open framework with one-dimensional elliptical channels and r- and l-helical chains, and their resulting frameworks can be rationalized as crb and pts topology respectively. an interesting feature of complex 3 is the presence of the linear cu-3 units that is formed by carboxylate and mu(2)-hydroxyl groups linking three cu(ii) metal centers. magnetic investigations indicate that ferromagnetic couplings are dominant in the three compounds.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000282006200034
公开日期	2012-04-25
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/43458]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Su SQ,Guo ZY,Li GH,et al. Tetracarboxylate-based Co(II), Ni(II) and Cu(II) three-dimensional coordination polymers: syntheses, structures and magnetic properties[J]. dalton transactions,2010,39(38):9123-9130.
APA	Su SQ.,Guo ZY.,Li GH.,Deng RP.,Song SY.,...&Zhang HJ.(2010).Tetracarboxylate-based Co(II), Ni(II) and Cu(II) three-dimensional coordination polymers: syntheses, structures and magnetic properties.dalton transactions,39(38),9123-9130.
MLA	Su SQ,et al."Tetracarboxylate-based Co(II), Ni(II) and Cu(II) three-dimensional coordination polymers: syntheses, structures and magnetic properties".dalton transactions 39.38(2010):9123-9130.