Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst

doi:10.1039/C9RA08560B

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	Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst
	Stéphane Streiff 1; Feng, Shi 2; Hangkong, Yuan2 ; Bright T. Kusema 1; Zhen, Yan 1
刊名	RSC Advances
	2019-11
卷号	9 期号:66 页码:38877 - 38881
关键词	2,5-bis(aminomethyl)furan 5-(hydroxymethyl)furfural bifunctional catalyst CuNiAlOx amination
DOI	10.1039/C9RA08560B
英文摘要	The development of facile protocols for the selective synthesis of biomass-derived diamine is a highly desirable pursuit in the field of heterogeneous catalysis. Herein, a simple and highly efficient bi-functional CuNiAlO_xcatalyst was developed for the one pot transformation of 5-(hydroxymethyl)furfural (5-HMF) into 2,5-bis(aminomethyl)furan (BAF) using a two-stage reaction process. Cu₄Ni₁Al₄O_x was found to be the most effective catalyst for this reaction, affording BAF in 85.9% yield. Our results could promote controllable conversion and utilization of biomass resource.
URL标识	查看原文
语种	英语
内容类型	期刊论文
源URL	[http://ir.licp.cn/handle/362003/25965]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Feng, Shi; Bright T. Kusema
作者单位	1.Eco-Efficient Products and Processes Laboratory (E2P2L), UMI 3464 CNRS-Solvay 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences
推荐引用方式 GB/T 7714	Stéphane Streiff,Feng, Shi,Hangkong, Yuan,et al. Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst[J]. RSC Advances,2019,9(66):38877 - 38881.
APA	Stéphane Streiff,Feng, Shi,Hangkong, Yuan,Bright T. Kusema,&Zhen, Yan.(2019).Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst.RSC Advances,9(66),38877 - 38881.
MLA	Stéphane Streiff,et al."Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst".RSC Advances 9.66(2019):38877 - 38881.