A novel metal-organic framework based on hexanuclear Co(ii) clusters as an anode material for lithium-ion batteries

	A novel metal-organic framework based on hexanuclear Co(ii) clusters as an anode material for lithium-ion batteries
	He, Yuan-Chun; Yu, Yang; Wang, Lingyan; Yang, Jiaqin; Kan, Wei-Qiu; Yang, Yan; Fan, Yao-Yao; Jing, Zhihong; You, Jinmao
刊名	CRYSTENGCOMM
	2018
卷号	20 期号:37
英文摘要	A new metal-organic framework, [Co(L)]center dot 1.5H(2)O (1), has been successfully synthesized from an organic ligand, 3-carboxy-1-(4'-carboxybenzyl)-2-oxidopyridinium. Compound 1 displays a novel 3D framework with a capsule-shaped cavity and a hexanuclear [Co-6] cluster. The temperature-dependent magnetic susceptibility of compound 1 has been investigated. The electrochemical application of compound 1 as a lithium-ion battery anode material was also explored. To improve the electrochemical performance of compound 1, we utilized compound 1 as a novel precursor to prepare a Co3O4@C composite. By comparison, the Co3O4@C composite shows a higher capacity and better cycling performance, which provides a new direction for the design of anode materials for lithium-ion batteries.
内容类型	期刊论文
源URL	[http://210.75.249.4/handle/363003/59955]
专题	西北高原生物研究所_中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	He, Yuan-Chun,Yu, Yang,Wang, Lingyan,et al. A novel metal-organic framework based on hexanuclear Co(ii) clusters as an anode material for lithium-ion batteries[J]. CRYSTENGCOMM,2018,20(37).
APA	He, Yuan-Chun.,Yu, Yang.,Wang, Lingyan.,Yang, Jiaqin.,Kan, Wei-Qiu.,...&You, Jinmao.(2018).A novel metal-organic framework based on hexanuclear Co(ii) clusters as an anode material for lithium-ion batteries.CRYSTENGCOMM,20(37).
MLA	He, Yuan-Chun,et al."A novel metal-organic framework based on hexanuclear Co(ii) clusters as an anode material for lithium-ion batteries".CRYSTENGCOMM 20.37(2018).