Gas-phase chemistry of ruthenium and rhodium carbonyl complexes

doi:10.1039/c5cp05670e

	Gas-phase chemistry of ruthenium and rhodium carbonyl complexes
	Qin, Zhi1 ; Haba, Hiromitsu 2; Komori, Yukiko 2; Wu, Xiaolei 1; Tan, Cunmin 1,3,4; Zhang, Xin 1,3; Fan, Fangli 1; Cao, Shiwei 1,3; Wang, Yang 1,3,4
刊名	PHYSICAL CHEMISTRY CHEMICAL PHYSICS
	2016-01-07
卷号	18 页码:119-125
ISSN号	1463-9076
DOI	10.1039/c5cp05670e
英文摘要	Short-lived ruthenium and rhodium isotopes were produced from a Cf-252 spontaneous fission (SF) source. Their volatile carbonyl complexes were formed in gas-phase reactions in situ with the carbon monoxide containing gas. A gas-jet system was employed to transport the volatile carbonyls from the recoil chamber to the chemical separation apparatus. The gas-phase chemical behaviors of these carbonyl complexes were studied using an online low temperature isothermal chromatography (IC) technique. Long IC columns made up of FEP Teflon were used to obtain the chemical information of the high-volatile Ru and Rh carbonyls. By excluding the influence of precursor effects, short-lived isotopes of Ru109-110 and Rh111-112 were used to represent the chemical behaviours of Ru and Rh carbonyls. Relative chemical yields of about 75% and 20% were measured for Ru(CO)(5) and Rh(CO)(4), respectively, relative to the yields of KCl aerosols transported in Ar gas. The adsorption enthalpies of ruthenium and rhodium carbonyl complexes on a Teflon surface were determined to be around Delta H-ads = -33(-2)(+1) kJ mol(-1) and -36(-1)(+2) kJ mol(-1), respectively, by fitting the breakthrough curves of the corresponding carbonyl complexes with a Monte Carlo simulation program. Different from Mo and Tc carbonyls, a small amount of oxygen gas was found to be not effective for the chemical yields of ruthenium and rhodium carbonyl complexes. The general chemical behaviors of short-lived carbonyl complexes of group VI-IX elements were discussed, which can be used in the future study on the gas-phase chemistry of superheavy elements - Bh, Hs, and Mt carbonyls.
资助项目	National natural Science Foundation of China[11079006] ; National natural Science Foundation of China[11505250] ; National natural Science Foundation of China[11575260] ; West Light Foundation of Chinese Academy of Sciences (CAS)
WOS关键词	TECHNETIUM ; SEABORGIUM ; CHROMATOGRAPHY ; ELEMENTS
WOS研究方向	Chemistry ; Physics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000368755500012
资助机构	National natural Science Foundation of China ; West Light Foundation of Chinese Academy of Sciences (CAS)
内容类型	期刊论文
源URL	[http://119.78.100.186/handle/113462/41533]
专题	近代物理研究所_实验物理中心
通讯作者	Qin, Zhi
作者单位	1.Chinese Acad Sci, Nucl Chem, Inst Modern Phys, 509 Nanchang Rd, Lanzhou 730000, Peoples R China 2.RIKEN, Nishina Ctr Accelerator Based Sci, Wako, Saitama 3510198, Japan 3.Univ Chinese Acad Sci, Sch Phys Sci & Technol, 19A Yuquan Rd, Beijing 100049, Peoples R China 4.Lanzhou Univ, Sch Nucl Sci & Technol, 222 Tianshuinan Rd, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Qin, Zhi,Haba, Hiromitsu,Komori, Yukiko,et al. Gas-phase chemistry of ruthenium and rhodium carbonyl complexes[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2016,18:119-125.
APA	Qin, Zhi.,Haba, Hiromitsu.,Komori, Yukiko.,Wu, Xiaolei.,Tan, Cunmin.,...&Wang, Yang.(2016).Gas-phase chemistry of ruthenium and rhodium carbonyl complexes.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,18,119-125.
MLA	Qin, Zhi,et al."Gas-phase chemistry of ruthenium and rhodium carbonyl complexes".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 18(2016):119-125.