Analysis of Contents and Distribution Patterns of Rare Earth Elements in the Surface Sediments of the South Mid-Atlantic Ridge
Li Jing-Xi1,2; Zhu Zhi-Wei1; Yin Xiao-Fei1; Han Bin1; Zheng Li1; Wang Jiang-Tao2; Wang Xiao-Ru1
刊名CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
2015-01
卷号43期号:1页码:21-26
关键词Southern Atlantic Rare earth element Inductively coupled plasma-mass spectrometry Sediments
ISSN号0253-3820
DOI10.1016/S1872-2040(15)60796-4
英文摘要A microwave digestion system was employed to digest sediment samples from 16 stations in the South Mid-Atlantic Ridge with HNO3-H2O2-HF as the digestion reagent. Rare earth elements (REEs) in the sediments were determined through inductively coupled plasma-mass spectrometry (ICP-MS), and the REE distribution characteristics were studied. The microwave digestion-ICP-MS method was used to determine the REEs with significant linear relationships (r = 0.9997-1.0000) for each element. The detection limit was at ng L-1 level, with relative standard deviation (RSD, n = 3) of less than 3% and the relative error within 6%. Moreover, the total amount of REEs (Sigma REEs) in the sediment samples from the 16 stations ranged from 37.25 to 134.8 mu g g(-1), the ratio range of the light/heavy REEs (LREEs/HREEs) was 0.61-1.70, the average value was 1.27, and the enrichment light rare earth elements in sediments was obvious. The REE distribution patterns in each station were similar, with obvious fractionation between the LREEs and HREEs. The REE distribution patterns in the sediments from different sources were also similar, but those between the terrestrial and marine sediments exhibited slight differences. The delta Eu and delta Ce in the sediments had negative anomalies, which showed that the REEs in the sediments originated from seawater. The content and distribution of the REEs in the South Atlantic were initially investigated in this study to provide data and technical support for the further study of REE distributions in the Atlantic region.
资助项目Basic Scientific Fund for National Public Research Institutes of China[2013G34]
WOS研究方向Chemistry
语种英语
出版者ELSEVIER SCIENCE INC
WOS记录号WOS:000347616700003
内容类型期刊论文
源URL[http://ir.fio.com.cn/handle/2SI8HI0U/3721]  
专题业务部门_海洋地质与地球物理研究室
作者单位1.State Ocean Adm, Inst Oceanog 1, Marine Ecol Res Ctr, Qingdao 266061, Shandong, Peoples R China;
2.Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Shandong, Peoples R China
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Li Jing-Xi,Zhu Zhi-Wei,Yin Xiao-Fei,et al. Analysis of Contents and Distribution Patterns of Rare Earth Elements in the Surface Sediments of the South Mid-Atlantic Ridge[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2015,43(1):21-26.
APA Li Jing-Xi.,Zhu Zhi-Wei.,Yin Xiao-Fei.,Han Bin.,Zheng Li.,...&Wang Xiao-Ru.(2015).Analysis of Contents and Distribution Patterns of Rare Earth Elements in the Surface Sediments of the South Mid-Atlantic Ridge.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,43(1),21-26.
MLA Li Jing-Xi,et al."Analysis of Contents and Distribution Patterns of Rare Earth Elements in the Surface Sediments of the South Mid-Atlantic Ridge".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 43.1(2015):21-26.
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