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Polymer-Coated Graphene Aerogel Beads and Supercapacitor Application
Ouyang, An ; Cao, Anyuan ; Hu, Song ; Li, Yanhui ; Xu, Ruiqiao ; Wei, Jinquan ; Zhu, Hongwei ; Wu, Dehai
刊名ACS APPLIED MATERIALS & INTERFACES
2016
关键词graphene beads freeze casting sandwich structure composite beads supercapacitor CARBON NANOTUBES ENERGY-STORAGE OXIDE NANOCOMPOSITES ARCHITECTURES PERFORMANCE COMPOSITES ELECTRODES DEPOSITION MONOLITHS
DOI10.1021/acsami.6b01965
英文摘要Graphene aerogels are highly porous materials with many energy and environmental applications; tailoring the structure and composition of pore walls within the aerogel is the key to those applications. Here, by freeze casting the graphene oxide sheets, we directly fabricated freestanding porous graphene beads containing radially oriented through channels from the sphere center to its surface. Furthermore, we introduced pseudopolymer to make reinforced, functional composite beads with a unique pore morphology. We showed that polymer layers can be coated smoothly on both sides of the pore walls, as well as on the junctions between adjacent pores, resulting in uniform polymer-graphene-polymer sandwiched structures (skeletons) throughout the bead. These composite beads significantly improved the electrochemical properties, with specific capacitances up to 669 Fig and good cyclic stability. Our results indicate that controlled fabrication of homogeneous hierarchical structures is a potential route toward high performance composite electrodes for various energy applications.; National Natural Science Foundation of China (NSFC) [51325202]; SCI(E); EI; PubMed; ARTICLE; anyuan@pku.edu.cn; 17; 11179-11187; 8
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/434196]  
专题工学院
推荐引用方式
GB/T 7714
Ouyang, An,Cao, Anyuan,Hu, Song,et al. Polymer-Coated Graphene Aerogel Beads and Supercapacitor Application[J]. ACS APPLIED MATERIALS & INTERFACES,2016.
APA Ouyang, An.,Cao, Anyuan.,Hu, Song.,Li, Yanhui.,Xu, Ruiqiao.,...&Wu, Dehai.(2016).Polymer-Coated Graphene Aerogel Beads and Supercapacitor Application.ACS APPLIED MATERIALS & INTERFACES.
MLA Ouyang, An,et al."Polymer-Coated Graphene Aerogel Beads and Supercapacitor Application".ACS APPLIED MATERIALS & INTERFACES (2016).
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