An online monitoring system for atmospheric nitrous acid (HONO) based on   stripping coil and ion chromatography

doi:10.1016/S1001-0742(12)60251-4

CORC > 北京大学 > 环境科学与工程学院

	An online monitoring system for atmospheric nitrous acid (HONO) based on stripping coil and ion chromatography
	Cheng, Peng ; Cheng, Yafang ; Lu, Keding ; Su, Hang ; Yang, Qiang ; Zou, Yikan ; Zhao, Yanran ; Dong, Huabing ; Zeng, Limin ; Zhang, Yuanhang
刊名	journal of environmental sciences china
	2013
关键词	interferences intercomparison EFFLUENT DIFFUSION DENUDER NITRIC-ACID AMBIENT AIR HETEROGENEOUS HYDROLYSIS PEROXYACETYL NITRATE AEROSOL COLLECTOR AQUEOUS-SOLUTION TECHNICAL NOTE WET DENUDER OH RADICALS
DOI	10.1016/S1001-0742(12)60251-4
英文摘要	A new instrument for measuring atmospheric nitrous acid (HONO) was developed, consisting of a double-wall glass stripping coil sampler coupled with ion chromatography (SC-IC). SC-IC is featured by small size (50 x 35 x 25 cm) and modular construction, including three independent parts: the sampling unit, the transfer and supporting unit, and the detection unit. High collection efficiency (> 99%) was achieved with 25 mu mol/L Na2CO3 as absorption solution even in the presence of highly acidic compounds. This instrument has a detection limit of 8 pptv at 15 min time resolution, with a measurement uncertainty of 7%. Potential interferences from NOx, NO2+SO2, NO2+VOCs, HONO+O-3, HNO3, peroxyacetyl nitrite (PAN) and particle nitrite were quantified in laboratory studies and were found to be insignificant under typical atmospheric conditions. Within the framework of the 3C-STAR project, inter-comparison between the SC-IC and LOPAP (long path liquid absorption photometer) was conducted at a rural site in the Pearl River Delta. Good agreement was achieved between the two instruments over three weeks. Both instruments determined a clear diurnal profile of ambient HONO concentrations from 0.1 to 2.5 ppbv. However, deviations were found for low ambient HONO concentrations (i.e. < 0.3 ppbv), which cannot be explained by previous investigated interference species. To accurately determine the HONO budget under illuminated conditions, more intercomparison of HONO measurement techniques is still needed in future studies, especially at low HONO concentrations.; Environmental Sciences; SCI(E); EI; PubMed; 2; 5; 895-907; 25
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/158782]
专题	环境科学与工程学院
推荐引用方式 GB/T 7714	Cheng, Peng,Cheng, Yafang,Lu, Keding,et al. An online monitoring system for atmospheric nitrous acid (HONO) based on stripping coil and ion chromatography[J]. journal of environmental sciences china,2013.
APA	Cheng, Peng.,Cheng, Yafang.,Lu, Keding.,Su, Hang.,Yang, Qiang.,...&Zhang, Yuanhang.(2013).An online monitoring system for atmospheric nitrous acid (HONO) based on stripping coil and ion chromatography.journal of environmental sciences china.
MLA	Cheng, Peng,et al."An online monitoring system for atmospheric nitrous acid (HONO) based on stripping coil and ion chromatography".journal of environmental sciences china (2013).