Light induced catalytic hydrodefluorination of perfluoroarenes by   porphyrin rhodium

doi:10.1039/c5qi00269a

CORC > 北京大学 > 化学与分子工程学院

	Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium
	Liu, Xu ; Wang, Zikuan ; Zhao, Xianyuan ; Fu, Xuefeng
刊名	INORGANIC CHEMISTRY FRONTIERS
	2016
关键词	F BOND ACTIVATION TRANSITION-METAL-COMPLEXES CARBON-FLUORINE BONDS HETEROCYCLIC CARBENE COMPLEXES C-F OXIDATIVE ADDITION NUCLEOPHILIC-SUBSTITUTION C(SP(3))-F BONDS AQUEOUS-SOLUTION FLUOROPYRIDINES
DOI	10.1039/c5qi00269a
英文摘要	Fluorine-containing organic compounds are essential building blocks that have been extensively employed in materials chemistry, medicinal chemistry as well as agrochemistry.(1) Simple perfluorinated bulk chemicals are easily accessible on an industrial scale, whereas the selective cleavage of C-F bonds of perfluorinated compounds is regarded as a promising approach to access partially fluorinated compounds.(1d-h) However, this defluorination process has been considered as one of the greatest challenges for synthetic chemistry due to the relative inertness of the C-F bond.(2); National Science Foundation of China [21322108, 21321001]; SCI(E); ARTICLE; fuxf@pku.edu.cn; 6; 861-865; 3
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/492554]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Liu, Xu,Wang, Zikuan,Zhao, Xianyuan,et al. Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium[J]. INORGANIC CHEMISTRY FRONTIERS,2016.
APA	Liu, Xu,Wang, Zikuan,Zhao, Xianyuan,&Fu, Xuefeng.(2016).Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium.INORGANIC CHEMISTRY FRONTIERS.
MLA	Liu, Xu,et al."Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium".INORGANIC CHEMISTRY FRONTIERS (2016).