Synthesis and reactivity of tetraalkoxyl[60]fullerene epoxides,   C-60(O)(OR)(4)

doi:10.1139/cjc-2016-0394

CORC > 北京大学 > 化学与分子工程学院

	Synthesis and reactivity of tetraalkoxyl[60]fullerene epoxides, C-60(O)(OR)(4)
	Lou, Ning ; Gan, Liangbing
刊名	CANADIAN JOURNAL OF CHEMISTRY
	2017
关键词	fullerene open cage cuprous iodide epoxide CHLOROFULLERENE C60CL6 TERMINAL ALKYNES FULLERENE DERIVATIVES CATALYZED IODINATION EFFICIENT SYNTHESIS SELECTIVE SYNTHESIS ARYL FUNCTIONALIZATION C-60 SUBSTITUTION
DOI	10.1139/cjc-2016-0394
英文摘要	Hexachloro[60]fullerene, C60Cl6, was reacted with a mixture of ROH/H2O (R = Me, Et, n-Pr, (CH2)(2)C CH) to form both C60Cl(OH)(OR)(4) and C60Cl(OR)(5). Only the C60Cl(OH)(OR)(4) were isolated with bulky alcohols, ROH (R = (CH2)(3)C CH, (CH2)(4)C CH). Tetrahydro[60]fullerene epoxides, C-60(O)(OR)(4), were prepared by treating C60Cl(OH)(OR)(4) with CuI. The epoxy moiety could be hydrolyzed to the vicinal diol derivatives, C-60(OH)(2)(OR)(4), and then oxidized to form dicarbonyl open-cage fullerenes, C60O2(OR)(4). CuI was found to convert the terminal alkynyl addends into iodoalkynyl addends on the C-60 cage.; National Natural Science Foundation of China (NNSFC) [21272013, 21132007]; Ministry of Science and Technology of the People's Republic of China (MOST) [2011CB808401]; SCI(E); ARTICLE; 3,SI; 292-297; 95
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/474922]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Lou, Ning,Gan, Liangbing. Synthesis and reactivity of tetraalkoxyl[60]fullerene epoxides, C-60(O)(OR)(4)[J]. CANADIAN JOURNAL OF CHEMISTRY,2017.
APA	Lou, Ning,&Gan, Liangbing.(2017).Synthesis and reactivity of tetraalkoxyl[60]fullerene epoxides, C-60(O)(OR)(4).CANADIAN JOURNAL OF CHEMISTRY.
MLA	Lou, Ning,et al."Synthesis and reactivity of tetraalkoxyl[60]fullerene epoxides, C-60(O)(OR)(4)".CANADIAN JOURNAL OF CHEMISTRY (2017).