Custom Coordination Environments for Lanthanoids: Tripodal Ligands   Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based   Molecular Nanomagnets

doi:10.1021/acs.inorgchem.6b03118

CORC > 北京大学 > 化学与分子工程学院

	Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets
	Lim, Kwang Soo ; Baldovi, Jose J. ; Jiang, ShangDa ; Koo, Bong Ho ; Kang, Dong Won ; Lee, Woo Ram ; Koh, Eui Kwan ; Gaita-Arino, Alejandro ; Coronado, Eugenio ; Slota, Michael ; Bogani, Lapo ; Hong, Chang Seop
刊名	INORGANIC CHEMISTRY
	2017
关键词	SINGLE-ION MAGNETS SPIN QUBITS MAGNETIZATION RELAXATION QUANTUM COHERENCE COMPLEXES ANISOTROPY BEHAVIOR SYMMETRY DY(III) BARRIER
DOI	10.1021/acs.inorgchem.6b03118
英文摘要	Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We perform a complete experimental and theoretical investigation of their magnetic properties, including a full single-crystal magnetic anisotropy analysis. The combination of electrostatic and crystal-field computational tools (SIMPRE and CONDON codes) allows us to explain the static behavior of these systems in detail.; Korean Basic Science Research Program [NRF-2015R1A2A1A10055658]; KCRC grant [NRF-2012-0008901]; Korean Priority Research Centers Program [NRF2010-0020209]; EU [ERC-CoG-647301 DECRESIM, ERC-StG-338258 OptoQMol, COST Action 15128 MOLSPIN]; Spanish MINECO [MAT2014-56143-R, CTQ2014-52758-P]; Spanish MINECO (Excellence Unit Maria de Maeztu) [MDM-2015-0538]; Generalitat Valenciana (Prometeo Programme of excellence); MINECO (Ramon y Cajal contract); SCI(E); ARTICLE; 9; 4911-4917; 56
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/473699]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Lim, Kwang Soo,Baldovi, Jose J.,Jiang, ShangDa,et al. Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets[J]. INORGANIC CHEMISTRY,2017.
APA	Lim, Kwang Soo.,Baldovi, Jose J..,Jiang, ShangDa.,Koo, Bong Ho.,Kang, Dong Won.,...&Hong, Chang Seop.(2017).Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets.INORGANIC CHEMISTRY.
MLA	Lim, Kwang Soo,et al."Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets".INORGANIC CHEMISTRY (2017).