Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N( NH)]R | |
Xu, Dan ; Li, Yanbang ; Lou, Ning ; Gan, Liangbing | |
刊名 | ORGANIC CHEMISTRY FRONTIERS |
2017 | |
关键词 | FULLERENE-MIXED PEROXIDES C-60 DERIVATIVES HETEROFULLERENES INTERCONVERSION AZAFULLERENE AZIRIDINOFULLERENE FULLEROIDS ADDITIONS C59N |
DOI | 10.1039/c7qo00098g |
英文摘要 | The selective insertion of a CH2 or NH group at the 5,6-junction on the C59N skeleton is achieved through the PCl5 induced reaction of a CH2OH or NHOH group on the cage to form [C59N( CH2)]R or [C59N(NH)] R, respectively. Spectroscopic data and single crystal X-ray diffraction structure analysis confirmed the 5,6-open homoazafullerene structure.; NSFC [21672009, 21132007]; Major State Basic Research Development Program [2015CB856600]; SCI(E); ARTICLE; 5; 750-754; 4 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/473538] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Xu, Dan,Li, Yanbang,Lou, Ning,et al. Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N( NH)]R[J]. ORGANIC CHEMISTRY FRONTIERS,2017. |
APA | Xu, Dan,Li, Yanbang,Lou, Ning,&Gan, Liangbing.(2017).Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N( NH)]R.ORGANIC CHEMISTRY FRONTIERS. |
MLA | Xu, Dan,et al."Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N( NH)]R".ORGANIC CHEMISTRY FRONTIERS (2017). |
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