Nonconventional Luminescence Enhanced by Silicone-Induced Aggregation | |
Lu, Hang ; Hu, Ziqi ; Feng, Shengyu | |
刊名 | CHEMISTRY-AN ASIAN JOURNAL |
2017 | |
关键词 | aggregation nonconventional luminogens photophysics silicon STRONG BLUE PHOTOLUMINESCENCE INDUCED EMISSION SILOXANE-POLY(AMIDOAMINE) DENDRIMERS UNCONVENTIONAL CHROMOPHORES PAMAM DENDRIMERS CLICK CHEMISTRY FLUORESCENCE HYDROXYL THIOL |
DOI | 10.1002/asia.201700234 |
英文摘要 | Nonconventional organic luminogens have attracted a great deal of interests owing to their intriguing properties (e.g., unusual fluorescence emission) and promising applications. According to previous studies, it was found that introduction of Si-O could enhance the fluorescence emission of the luminogens. Herein, we have synthesized some fluorescent siloxane derivatives and similar molecules without Si-O units by simple and efficient modification to investigate the role of Si-O units in the emission. It was found that the strong emission could be observed in dilute solutions of siloxane derivatives, but not in the carbon compounds. UV/Vis absorption, fluorescence spectra, nuclear magnetic resonance spectra, and theoretical calculations indicated that the heteroatom and the Si-O unit formed the coordination bond in the siloxane derivatives, resulting in enhanced fluorescence emission.; National Natural Science Foundation of China [21274080, 21502105]; Natural Science Foundation of Shandong Province [ZR2015BQ008]; Shandong Special Fund for Independent Innovation and Achievements transformation [2014ZZCX01101]; SCI(E); ARTICLE; 11,SI; 1213-1217; 12 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/473115] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Lu, Hang,Hu, Ziqi,Feng, Shengyu. Nonconventional Luminescence Enhanced by Silicone-Induced Aggregation[J]. CHEMISTRY-AN ASIAN JOURNAL,2017. |
APA | Lu, Hang,Hu, Ziqi,&Feng, Shengyu.(2017).Nonconventional Luminescence Enhanced by Silicone-Induced Aggregation.CHEMISTRY-AN ASIAN JOURNAL. |
MLA | Lu, Hang,et al."Nonconventional Luminescence Enhanced by Silicone-Induced Aggregation".CHEMISTRY-AN ASIAN JOURNAL (2017). |
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