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Nonconventional Luminescence Enhanced by Silicone-Induced Aggregation
Lu, Hang ; Hu, Ziqi ; Feng, Shengyu
刊名CHEMISTRY-AN ASIAN JOURNAL
2017
关键词aggregation nonconventional luminogens photophysics silicon STRONG BLUE PHOTOLUMINESCENCE INDUCED EMISSION SILOXANE-POLY(AMIDOAMINE) DENDRIMERS UNCONVENTIONAL CHROMOPHORES PAMAM DENDRIMERS CLICK CHEMISTRY FLUORESCENCE HYDROXYL THIOL
DOI10.1002/asia.201700234
英文摘要Nonconventional organic luminogens have attracted a great deal of interests owing to their intriguing properties (e.g., unusual fluorescence emission) and promising applications. According to previous studies, it was found that introduction of Si-O could enhance the fluorescence emission of the luminogens. Herein, we have synthesized some fluorescent siloxane derivatives and similar molecules without Si-O units by simple and efficient modification to investigate the role of Si-O units in the emission. It was found that the strong emission could be observed in dilute solutions of siloxane derivatives, but not in the carbon compounds. UV/Vis absorption, fluorescence spectra, nuclear magnetic resonance spectra, and theoretical calculations indicated that the heteroatom and the Si-O unit formed the coordination bond in the siloxane derivatives, resulting in enhanced fluorescence emission.; National Natural Science Foundation of China [21274080, 21502105]; Natural Science Foundation of Shandong Province [ZR2015BQ008]; Shandong Special Fund for Independent Innovation and Achievements transformation [2014ZZCX01101]; SCI(E); ARTICLE; 11,SI; 1213-1217; 12
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/473115]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Lu, Hang,Hu, Ziqi,Feng, Shengyu. Nonconventional Luminescence Enhanced by Silicone-Induced Aggregation[J]. CHEMISTRY-AN ASIAN JOURNAL,2017.
APA Lu, Hang,Hu, Ziqi,&Feng, Shengyu.(2017).Nonconventional Luminescence Enhanced by Silicone-Induced Aggregation.CHEMISTRY-AN ASIAN JOURNAL.
MLA Lu, Hang,et al."Nonconventional Luminescence Enhanced by Silicone-Induced Aggregation".CHEMISTRY-AN ASIAN JOURNAL (2017).
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