Beyond carbocations: Synthesis, structure and reactivity of heavier   Group 14 element cations

doi:10.1016/j.ccr.2016.11.017

CORC > 北京大学 > 化学与分子工程学院

	Beyond carbocations: Synthesis, structure and reactivity of heavier Group 14 element cations
	Fang, Huayi ; Wang, Zikuan ; Fu, Xuefeng
刊名	COORDINATION CHEMISTRY REVIEWS
	2017
关键词	Main group chemistry Heavier Group 14 element cation Synthesis strategy Structure Reactivity FRUSTRATED LEWIS PAIR MAIN-GROUP ELEMENTS FREE SILYLIUM ION ORGANOTIN(II) CATION CRYSTAL-STRUCTURES FACILE ACCESS PENTAMETHYLCYCLOPENTADIENYLSILICON(II) CATION GERMANIUM(II) DICATIONS LIVING POLYMERIZATION DIHYDROGEN ACTIVATION
DOI	10.1016/j.ccr.2016.11.017
英文摘要	Carbocations represent one of the most active organic compounds. Many efforts have been paid in extending the chemistry of carbocations down the group to the heavier elements (Si, Ge, Sn and Pb). It has long been known that elements in a group share very similar properties, such as the coordination geometry and reactivity. The first results on heavier Group 14 element cations that appeared at the end of the past century corroborated this rule. However, a large number of novel heavier Group 14 element cations, many of which displayed very different coordination geometry and frontier orbital configurations compared to classical carbocations, have been synthesized in recent years utilizing specially designed ligands. As a result of the novel structure and frontier orbital configuration, some of the newly reported heavier Group 14 element cations have been used in catalysis, bond activation and small molecule activation. This review focused on the survey of synthesis, structure and reactivity of the recently reported heavier Group 14 element cations. (C) 2016 Elsevier B.V. All rights reserved.; National Science Foundation of China [21322108, 21321001]; SCI(E); REVIEW; 214-237; 344
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/471968]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Fang, Huayi,Wang, Zikuan,Fu, Xuefeng. Beyond carbocations: Synthesis, structure and reactivity of heavier Group 14 element cations[J]. COORDINATION CHEMISTRY REVIEWS,2017.
APA	Fang, Huayi,Wang, Zikuan,&Fu, Xuefeng.(2017).Beyond carbocations: Synthesis, structure and reactivity of heavier Group 14 element cations.COORDINATION CHEMISTRY REVIEWS.
MLA	Fang, Huayi,et al."Beyond carbocations: Synthesis, structure and reactivity of heavier Group 14 element cations".COORDINATION CHEMISTRY REVIEWS (2017).