[60]Fullerene-Based Macrocycle Ligands | |
Li, Yanbang ; Gan, Liangbing | |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL |
2017 | |
关键词 | curved pi-systems fullerene heterocycle macrocycle OPEN-CAGE FULLERENES C-60 DERIVATIVES CHEMICAL-SYNTHESIS MILD CONDITIONS CARBON-ATOM ORIFICE HETEROFULLERENES ENCAPSULATION |
DOI | 10.1002/chem.201701526 |
英文摘要 | Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C-60 could lead to various macrocycle ligands with a cage-shaped backbone. Theoretical calculations indicate that such C-60-based macrocycle ligands are as stable as C-60 thermodynamically according to their similar HOMO-LUMO gaps. The synthesis of these ligands is a challenging task. Nevertheless important progresses have been reported. This concept article focuses on the structures of possible C-60-based macrocycle ligands and related synthetic results.; NNSFC [21672009]; MOST [2011CB808401]; SCI(E); ARTICLE; 44; 10485-10490; 23 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/471594] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Li, Yanbang,Gan, Liangbing. [60]Fullerene-Based Macrocycle Ligands[J]. CHEMISTRY-A EUROPEAN JOURNAL,2017. |
APA | Li, Yanbang,&Gan, Liangbing.(2017).[60]Fullerene-Based Macrocycle Ligands.CHEMISTRY-A EUROPEAN JOURNAL. |
MLA | Li, Yanbang,et al."[60]Fullerene-Based Macrocycle Ligands".CHEMISTRY-A EUROPEAN JOURNAL (2017). |
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