Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene   Complexes through Carbene Migratory Insertion/Tsuji-Trost Reaction

doi:10.1002/anie.201707590

CORC > 北京大学 > 化学与分子工程学院

	Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji-Trost Reaction
	Wang, Kang ; Ping, Yifan ; Chang, Taiwei ; Wang, Jianbo
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2017
关键词	allylation annulation chromium(0) carbenes migratory insertions palladium catalysis ALPHA-DIAZOCARBONYL COMPOUNDS CROSS-COUPLING REACTIONS LATE TRANSITION-METALS N-TOSYLHYDRAZONES ALLYLIC SUBSTITUTION ORGANIC-SYNTHESIS SELF-DIMERIZATION TERMINAL ALKYNES DIAZO-COMPOUNDS BOND FORMATION
DOI	10.1002/anie.201707590
英文摘要	Vinyl chromium(0) Fischer carbene complexes were employed as the source of -allylic palladium species for catalytic [3+3] annulation under palladium catalysis. Mechanistically, this transformation is proposed to involve carbene migratory insertion and intramolecular Tsuji-Trost reaction as the key steps. Substituted six-membered heterocyclic flavonones and quinolines are obtained, depending on the nucleophilic functional group on the coupling partners.; National Basic Research Program of China (973 Program) [2015CB856600]; NSFC [21332002]; SCI(E); ARTICLE; 42; 13140-13144; 56
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/470484]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Kang,Ping, Yifan,Chang, Taiwei,et al. Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji-Trost Reaction[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017.
APA	Wang, Kang,Ping, Yifan,Chang, Taiwei,&Wang, Jianbo.(2017).Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji-Trost Reaction.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Wang, Kang,et al."Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji-Trost Reaction".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017).