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Enhanced catalytic performance of Ir catalysts supported on ceria-based solid solutions for methane dry reforming reaction
Wang, Fagen ; Xu, Leilei ; Yang, Juan ; Zhang, Jian ; Zhang, Longzhu ; Li, Hui ; Zhao, Yu ; Li, He Xing ; Wu, Kai ; Xu, Guo Qin ; Chen, Wei
2017
关键词Ir/Ce(0.9)Pro(0.1)O(2) Ir/Ce(0.9)Zro(0.1)O(2) Methane dry reforming Metal-support interaction CARBON-DIOXIDE HYDROGEN-PRODUCTION SYNTHESIS GAS SYNGAS PRODUCTION SURFACE-AREA CO2 OXIDATION DEACTIVATION CONVERSION STABILITY
英文摘要Methane dry reforming reaction was investigated over Ir catalysts supported on ceria-based solid solutions. The doping of Pr6O11 or ZrO2 into the matrix of ceria yields more oxygen defects, resulting in an improved redox property and enhanced metal-support interaction in Ir/Ce0.9M0.1O2 (M = Pr, Zr) catalysts compared to Ir/CeO2 catalyst. The Ir/Ce0.9M0.1O2 (M= Pr, Zr) catalysts showed higher catalytic performance and better stability than the Ir/CeO2 catalyst, which were assigned to positive effects of doping in maintaining Ir nanoparticles, stabilizing catalyst structure, and the strong metal-support interaction in reducing carbon deposition. (C) 2016 Elsevier B.V. All rights reserved.; CPCI-S(ISTP); ,SI; 295-303; 281
语种英语
出处13th International Conference on Carbon Dioxide Utilization (ICCDU)
DOI标识10.1016/j.cattod.2016.03.055
内容类型其他
源URL[http://ir.pku.edu.cn/handle/20.500.11897/469794]  
专题化学与分子工程学院
工学院
推荐引用方式
GB/T 7714
Wang, Fagen,Xu, Leilei,Yang, Juan,et al. Enhanced catalytic performance of Ir catalysts supported on ceria-based solid solutions for methane dry reforming reaction. 2017-01-01.
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