Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and   Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes

doi:10.1021/acs.organomet.6b00073

CORC > 北京大学 > 化学与分子工程学院

	Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes
	Wei, Baosheng ; Li, Heng ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	ORGANOMETALLICS
	2016
关键词	ALKALI-METAL COMPOUNDS DI-LITHIO REAGENTS STRUCTURAL-CHARACTERIZATION FACILE SYNTHESIS ORGANOMETALLIC COMPOUNDS COMPLEXES CATALYSTS ROUTE METALLOCENES REACTIVITY
DOI	10.1021/acs.organomet.6b00073
英文摘要	The development of Ca-mediated reactions is of great importance and is in great demand in both organometallic and organic chemistry. In this paper, we report that calcium iodide efficiently promotes the transformation of various 1,4-dilithio-1,3-butadienes into indenes or perfluorodibenzopentalenes, via an intramolecular C-H or C-F bond cleavage, respectively. In the reaction process, the Ca-induced s-cis/trans configurational isomerization of 1,4-dilithio-1,3-butadienes is followed by the subsequent nucleophilic C-H or C-F bond activation.; 973 Program [2012CB821600]; Natural Science Foundation of China (NSFC); SCI(E); EI; ARTICLE; wx_zhang@pku.edu.cn; zfxi@pku.edu.cn; 10; 1458-1463; 35
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/437238]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wei, Baosheng,Li, Heng,Zhang, Wen-Xiong,et al. Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes[J]. ORGANOMETALLICS,2016.
APA	Wei, Baosheng,Li, Heng,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2016).Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes.ORGANOMETALLICS.
MLA	Wei, Baosheng,et al."Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes".ORGANOMETALLICS (2016).