Oxide-Modified Nickel Photocatalysts for the Production of Hydrocarbons   in Visible Light

doi:10.1002/anie.201511334

CORC > 北京大学 > 化学与分子工程学院

	Oxide-Modified Nickel Photocatalysts for the Production of Hydrocarbons in Visible Light
	Zhao, Yufei ; Zhao, Bo ; Liu, Jinjia ; Chen, Guangbo ; Gao, Rui ; Yao, Siyu ; Li, Mengzhu ; Zhang, Qinghua ; Gu, Lin ; Xie, Jinglin ; Wen, Xiaodong ; Wu, Li-Zhu ; Tung, Chen-Ho ; Ma, Ding ; Zhang, Tierui
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2016
关键词	Fischer-Tropsch synthesis layered double hydroxides nickel photocatalysis ultrathin nanosheets FISCHER-TROPSCH SYNTHESIS TITANIA-SUPPORTED NICKEL CO HYDROGENATION CATALYSTS NANOCATALYSTS CONVERSION METHANE PHASE H-2
DOI	10.1002/anie.201511334
英文摘要	Metallic nickel nanostructures that were partially decorated by discrete nickel oxide layers were fabricated by insitu reduction of calcinated Ni-containing layered double hydroxide nanosheets, the structure of which was confirmed by extended X-ray absorption fine structure spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. The existence of the abundant interfaces between the surface Ni oxide overlayer and metallic Ni altered the geometric/electronic structure of the Ni nanoparticles, making them apt for CO activation under light irradiation. Most importantly, the unique structure favors the C-C coupling reaction on its surface, which confers the catalyst unexpected reaction power towards higher hydrocarbons at moderate reaction conditions. This study leads to a green and sustainable approach for the photocatalytic production of highly valuable chemical fuels.; Ministry of Science and Technology of China [2014CB239402, 2013CB933100, 2013CB834505]; Chinese Academy of Sciences [KGZD-EW-T05]; National Natural Science Foundation of China [1401206, 21473003, 21473229, 51322213, 21301183, 51172245, 91127005, 21401207, 91545121]; innovation foundation of the Institute of Coal Chemistry, Chinese Academy of Sciences; SCI(E); EI; PubMed; ARTICLE; wxd@sxicc.ac.cn; dma@pku.edu.cn; tierui@mail.ipc.ac.cn; 13; 4215-4219; 55
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/434751]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhao, Yufei,Zhao, Bo,Liu, Jinjia,et al. Oxide-Modified Nickel Photocatalysts for the Production of Hydrocarbons in Visible Light[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016.
APA	Zhao, Yufei.,Zhao, Bo.,Liu, Jinjia.,Chen, Guangbo.,Gao, Rui.,...&Zhang, Tierui.(2016).Oxide-Modified Nickel Photocatalysts for the Production of Hydrocarbons in Visible Light.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Zhao, Yufei,et al."Oxide-Modified Nickel Photocatalysts for the Production of Hydrocarbons in Visible Light".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016).