Toward Controlled Hierarchical Heterogeneities in Giant Molecules with   Precisely Arranged Nano Building Blocks

doi:10.1021/acscentsci.5b00385

CORC > 北京大学 > 化学与分子工程学院

	Toward Controlled Hierarchical Heterogeneities in Giant Molecules with Precisely Arranged Nano Building Blocks
	Zhang, Wei ; Huang, Mingjun ; Su, Hao ; Zhang, Siyu ; Yue, Kan ; Dong, Xue-Hui ; Li, Xiaopeng ; Liu, Hao ; Zhang, Shuo ; Wesdemiotis, Chrys ; Lotz, Bernard ; Zhang, Wen-Bin ; Li, Yiwen ; Cheng, Stephen Z. D.
刊名	ACS CENTRAL SCIENCE
	2016
关键词	JANUS PARTICLES PHASE SYNTHESIS SEQUENCE POLYMERS DESIGN MACROMOLECULES POLYMERIZATION SURFACTANTS ASSEMBLIES COPOLYMERS
DOI	10.1021/acscentsci.5b00385
英文摘要	Herein we introduce a unique synthetic methodology to prepare a library of giant molecules with multiple, precisely arranged nano building blocks, and illustrate the influence of minute structural differences on their self-assembly behaviors. The T-8 polyhedral oligomeric silsesquioxane (POSS) nanoparticles are orthogonally functionalized and sequentially attached onto the end of a hydrophobic polymer chain in either linear or branched configuration. The heterogeneity of primary chemical structure in terms of composition, surface functionality, sequence, and topology can be precisely controlled and is reflected in the self-assembled supramolecular structures of these giant molecules in the condensed state. This strategy offers promising opportunities to manipulate the hierarchical heterogeneities of giant molecules via precise and modular assemblies of various nano building blocks.; SCI(E); PubMed; ARTICLE; wenbin@pku.edu.cn; yl48@zips.uakron.edu; scheng@uakron.edu; 1; 48-54; 2
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/433794]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Wei,Huang, Mingjun,Su, Hao,et al. Toward Controlled Hierarchical Heterogeneities in Giant Molecules with Precisely Arranged Nano Building Blocks[J]. ACS CENTRAL SCIENCE,2016.
APA	Zhang, Wei.,Huang, Mingjun.,Su, Hao.,Zhang, Siyu.,Yue, Kan.,...&Cheng, Stephen Z. D..(2016).Toward Controlled Hierarchical Heterogeneities in Giant Molecules with Precisely Arranged Nano Building Blocks.ACS CENTRAL SCIENCE.
MLA	Zhang, Wei,et al."Toward Controlled Hierarchical Heterogeneities in Giant Molecules with Precisely Arranged Nano Building Blocks".ACS CENTRAL SCIENCE (2016).