A new strategy to improve the sensitivity and selectivity of dopamine detection | |
Xie, Xiang ; Gu, Jing ; Zhao, Wenbo ; Liu, Shujuan ; Qiao, Yonghui ; Zhu, Xinyu ; Yin, Xiaohong ; Zhu, Zhiwei ; Li, Meixian ; Shao, Yuanhua | |
刊名 | SCIENCE CHINA-CHEMISTRY |
2015 | |
关键词 | dopamine detection graphene/OMimPF(6)gel-modified electrode electrochemical microextraction square-wave voltammetric stripping GLASSY-CARBON ELECTRODE IONIC LIQUID ASCORBIC-ACID URIC-ACID SOLVENT-EXTRACTION CYCLIC VOLTAMMETRY AQUEOUS-SOLUTIONS COMPOSITE FILM ELECTROCHEMISTRY GRAPHENE |
DOI | 10.1007/s11426-014-5300-y |
英文摘要 | We applied the combination of in situ electrochemical liquid-phase microextraction and square-wave voltammetric stripping analysis for the first time as a highly sensitive and selective approach for the detection of dopamine. A mixed gel of graphene sheets and an ionic liquid of 1-octyl-3-methylimidazolium hexaflurophosphate (OMimPF(6)) was used as a micro liquid-phase to pre-concentrate dopamine by controlled potential electrolysis from an aqueous solution (as a donor phase), followed by square-wave voltammetric stripping detection. Under optimized conditions, a linear calibration curve was obtained in the range of 0.05 to 1.0 mu mol/L in the presence of excess ascorbic acid and uric acid. The detection limit has been found to be 8.0 nmol/L (S/N=3).; National Natural Science Foundation of China [21335001, 21075004]; SCI(E); EI; ARTICLE; xiexiangster@163.com; yhshao@pku.edu.cn; 5; 892-898; 58 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/420366] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Xie, Xiang,Gu, Jing,Zhao, Wenbo,et al. A new strategy to improve the sensitivity and selectivity of dopamine detection[J]. SCIENCE CHINA-CHEMISTRY,2015. |
APA | Xie, Xiang.,Gu, Jing.,Zhao, Wenbo.,Liu, Shujuan.,Qiao, Yonghui.,...&Shao, Yuanhua.(2015).A new strategy to improve the sensitivity and selectivity of dopamine detection.SCIENCE CHINA-CHEMISTRY. |
MLA | Xie, Xiang,et al."A new strategy to improve the sensitivity and selectivity of dopamine detection".SCIENCE CHINA-CHEMISTRY (2015). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论