2D Ln(III)Ru(2)(III) compounds constructed from   trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic   properties

doi:10.1021/ic060580m

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	2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties
	Yeung, Wai-Fun ; Lau, Tai-Chu ; Wang, Xin-Yi ; Gao, Song ; Szeto, Lap ; Wong, Wing-Tak
刊名	inorganic chemistry
	2006
关键词	NEAR-INFRARED LUMINESCENCE SINGLE-MOLECULE MAGNETS ONE-DIMENSIONAL CHAIN 4F-3D COORDINATION POLYMERS TRANSITION-METAL COMPLEXES LANTHANIDE ENERGY-TRANSFER PHOTOPHYSICAL PROPERTIES CRYSTAL-STRUCTURES PHOTOINDUCED MAGNETIZATION LN(3+)-M3+ COMPLEXES
DOI	10.1021/ic060580m
英文摘要	A series of cyano-bridged Ln(III)Ru(2)(III) coordination polymers, Ph4P {Ln(NO3)(2)[Ru(acac)(2)(CN)(2)](2)} [Ln = Tb (1), Dy (2), Er (3), Gd (4); Hacac = acetylacetone] have been synthesized by the reaction of Ln(NO3)(3) with trans-Ph4P[Ru(acac)(2)(CN)(2)] in methanol. X-ray crystallographic determination reveals that these compounds are isostructural and have a wavy (4,4) layer structure with the Ln(3+) ions bridged by trans-[Ru(acac)(2)(CN)(2)](-). Magnetic studies shows that the magnetic coupling between the Ln( III) and Ru( III) ions through the cyano bridges in 1-4 is negligibly weak.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000239723300035&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; SCI(E); 48; ARTICLE; 17; 6756-6760; 45
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/398416]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yeung, Wai-Fun,Lau, Tai-Chu,Wang, Xin-Yi,et al. 2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties[J]. inorganic chemistry,2006.
APA	Yeung, Wai-Fun,Lau, Tai-Chu,Wang, Xin-Yi,Gao, Song,Szeto, Lap,&Wong, Wing-Tak.(2006).2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties.inorganic chemistry.
MLA	Yeung, Wai-Fun,et al."2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties".inorganic chemistry (2006).