Highly Soluble Penta[(alkyl)dimethylsilylmethyl][60]fullerenes and Their   Ruthenium and Palladium Complexes

doi:10.1246/cl.2010.342

CORC > 北京大学 > 化学与分子工程学院

	Highly Soluble Penta[(alkyl)dimethylsilylmethyl][60]fullerenes and Their Ruthenium and Palladium Complexes
	Matsuo, Yutaka ; Muramatsu, Ayako ; Lu, Jiang ; Nakamura, Eiichi
刊名	chemistry letters
	2010
关键词	MOLECULES REAGENTS LIGAND WATER
DOI	10.1246/cl.2010.342
英文摘要	Copper-mediated fivefold addition of RMe2SiCH2MgCl to [60]fullerene produces C-60(CH2SiMe2R)(5)H (R = H, Et, n-Bu, and n-hexyl), which can be further converted into ruthenium and palladium complexes. These organofullerenes and metal-fullerene complexes, particularly when R = n-Hex, are highly soluble in various organic solvents, e.g., 107 mg mL(-1) solubility in EtOAc and >1000 mg mL(-1) in hexane, where C60Me5H is essentially insoluble.; Chemistry, Multidisciplinary; SCI(E); 1; ARTICLE; 4; 342-343; 39
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/395779]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Matsuo, Yutaka,Muramatsu, Ayako,Lu, Jiang,et al. Highly Soluble Penta[(alkyl)dimethylsilylmethyl][60]fullerenes and Their Ruthenium and Palladium Complexes[J]. chemistry letters,2010.
APA	Matsuo, Yutaka,Muramatsu, Ayako,Lu, Jiang,&Nakamura, Eiichi.(2010).Highly Soluble Penta[(alkyl)dimethylsilylmethyl][60]fullerenes and Their Ruthenium and Palladium Complexes.chemistry letters.
MLA	Matsuo, Yutaka,et al."Highly Soluble Penta[(alkyl)dimethylsilylmethyl][60]fullerenes and Their Ruthenium and Palladium Complexes".chemistry letters (2010).