Synthesis and electrochemical study of water-soluble lanthanide   porphyrins

CORC > 北京大学 > 化学与分子工程学院

	Synthesis and electrochemical study of water-soluble lanthanide porphyrins
	Zhuang, QK ; Gao, XX
刊名	中国稀土学报英文版
	1998
关键词	rare earths porphyrin lanthanide porphyrin electrode reaction mechanism COMPLEXES
英文摘要	The water-soluble tetra-p-sulfonatophenylporphyrinatolanthanide, [Ln . TPPS . OH . 2imidazole] . 3H(2)O (Ln = Tb similar to Yb), were synthesized and characterized. Their stability and complex constants were also studied and determined. The structural formula of the lanthanide porphyrins was proposed too. The lanthanide atom is sitting above the porphyrin plane. For the lanthanide porphyrin complexes, the complex becomes more stable and the reduction potential has a slight shift to more positive values as the atomic number increases from Tb to Yb. The mechanism of electrode processes for these lanthanidee porphyrin complexes were investigated in details.; Chemistry, Applied; SCI(E); EI; 0; ARTICLE; 4; 251-254; 16
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/389858]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhuang, QK,Gao, XX. Synthesis and electrochemical study of water-soluble lanthanide porphyrins[J]. 中国稀土学报英文版,1998.
APA	Zhuang, QK,&Gao, XX.(1998).Synthesis and electrochemical study of water-soluble lanthanide porphyrins.中国稀土学报英文版.
MLA	Zhuang, QK,et al."Synthesis and electrochemical study of water-soluble lanthanide porphyrins".中国稀土学报英文版 (1998).