Diffusion of Li+ ions in LiNi1/3Mn 1/3Co1/3O2 | |
Zhang, X. ; Mauger, A. ; Jiang, W.J. ; Groult, H. ; Julien, C.M. | |
2011 | |
英文摘要 | Electrochemical properties of LiNi1/3Mn1/3Co 1/3O2 powders have been investigated for a sample free on any impurity and cation mixing reduced to 1.3%. The discharge capacity decreases from 174 mAh/g (0.01C) to 133 mAh/g when cycled at a high current density of 3C-rate. The sample reaches high capacity of 146 mAh/g after 90 cycles when using 1C-rate for discharging, with high capacity retention of 97%. The diffusion coefficient of the Li+ ions has been determined as a function of the delithiation rate by GIT and EIS analysis. The diffusion coefficient is in the range 1011-1012 cm2/s, and goes through a maximum at intermediate delithiation rate. ?The Electrochemical Society.; EI; 0 |
语种 | 英语 |
DOI标识 | 10.1149/1.3654205 |
内容类型 | 其他 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/327423] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhang, X.,Mauger, A.,Jiang, W.J.,et al. Diffusion of Li+ ions in LiNi1/3Mn 1/3Co1/3O2. 2011-01-01. |
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