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Diffusion of Li+ ions in LiNi1/3Mn 1/3Co1/3O2
Zhang, X. ; Mauger, A. ; Jiang, W.J. ; Groult, H. ; Julien, C.M.
2011
英文摘要Electrochemical properties of LiNi1/3Mn1/3Co 1/3O2 powders have been investigated for a sample free on any impurity and cation mixing reduced to 1.3%. The discharge capacity decreases from 174 mAh/g (0.01C) to 133 mAh/g when cycled at a high current density of 3C-rate. The sample reaches high capacity of 146 mAh/g after 90 cycles when using 1C-rate for discharging, with high capacity retention of 97%. The diffusion coefficient of the Li+ ions has been determined as a function of the delithiation rate by GIT and EIS analysis. The diffusion coefficient is in the range 1011-1012 cm2/s, and goes through a maximum at intermediate delithiation rate. ?The Electrochemical Society.; EI; 0
语种英语
DOI标识10.1149/1.3654205
内容类型其他
源URL[http://ir.pku.edu.cn/handle/20.500.11897/327423]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Zhang, X.,Mauger, A.,Jiang, W.J.,et al. Diffusion of Li+ ions in LiNi1/3Mn 1/3Co1/3O2. 2011-01-01.
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