Self-assembled film of poly(4-carboxyphenyl)acetylene and diazoresin and its photoelectric conversion property | |
Yao, GJ ; Dong, YP ; Cao, TB ; Yang, SM ; Lam, JWY ; Tang, BZ | |
刊名 | 胶体与界面科学杂志
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2003 | |
关键词 | poly(4-carboxyphenyl)acetylene sodium salt diazoresin self-assembled multilayer films photoelectric conversion property BY-LAYER MANIPULATION CONJUGATED POLYMERS MULTILAYER FILMS POLYACETYLENE POLYANILINE ADSORPTION SURFACES RESINS DNA |
DOI | 10.1016/S0021-9797(02)00058-9 |
英文摘要 | A novel multilayer film was assembled from water-soluble poly(4-carboxyphenyl)acetylene sodium salt (PCPA) and diazoresin (DR) in aqueous solution via electrostatic attraction. Under UV irradiation, following the decomposition of the diazonium group between the adjacent interfaces of the multilayers, the ionic bonds of the self-assembled film convert to covalent bonds and the film becomes very stable toward electrolyte aqueous solutions. Thus, the photoelectric conversion property of PCPA-containing film can be measured in a conventional three-electrode photoelectrochemical cell, and 0.5 mol/l KCl solution can be used as the supporting electrolyte. The photocurrent spectroscopy response coincides with the absorption spectrum of the irradiated self-assembled film, which indicates that the irradiated DR/PCPA film is responsible for the photocurrent generation. (C) 2003 Elsevier Science (USA). All rights reserved.; Chemistry, Physical; SCI(E); EI; 0; ARTICLE; 2; 263-267; 257 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/256213] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Yao, GJ,Dong, YP,Cao, TB,et al. Self-assembled film of poly(4-carboxyphenyl)acetylene and diazoresin and its photoelectric conversion property[J]. 胶体与界面科学杂志,2003. |
APA | Yao, GJ,Dong, YP,Cao, TB,Yang, SM,Lam, JWY,&Tang, BZ.(2003).Self-assembled film of poly(4-carboxyphenyl)acetylene and diazoresin and its photoelectric conversion property.胶体与界面科学杂志. |
MLA | Yao, GJ,et al."Self-assembled film of poly(4-carboxyphenyl)acetylene and diazoresin and its photoelectric conversion property".胶体与界面科学杂志 (2003). |
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