Organic-inorganic hybrids: Preparation and structural characterization   of (Bu4N)(2)]Mo6O17(NAr)(2)] and (Bu4N)(2)[Mo6O18(NAr)] (Ar = o-CH3C6H4)

doi:10.1002/zaac.200400351

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	Organic-inorganic hybrids: Preparation and structural characterization of (Bu4N)(2)]Mo6O17(NAr)(2)] and (Bu4N)(2)[Mo6O18(NAr)] (Ar = o-CH3C6H4)
	Li, Q ; Wu, PF ; Wei, YG ; Xia, Y ; Wang, Y ; Guo, HY
刊名	zeitschrift fur anorganische und allgemeine chemie
	2005
关键词	organoimido derivatives polyoxometalates DCC organic-inorganic hybrids crystal structures ORGANOIMIDO DERIVATIVES AROMATIC-AMINES POLYOXOMETALATE HEXAMOLYBDATE FUNCTIONALIZATION EFFICIENT < LIGANDS MO6O19> 2
DOI	10.1002/zaac.200400351
英文摘要	In the presence of N,N '-dicyclohexylcarbodiimide (DCC), (Bu4N)(2)[Mo6O18(NAr)] (1) and (Bu4N)(2)[Mo6O17(NAr)(2)] (2), Ar = o-CH3C6H4, have been synthesized via the reaction of [alpha-Mo8O26](4-) with o-toluidine. If the hydrochloride salt of o-toluidine was added into the reactive mixture, only the monofunctionalized imido derivative of [Mo6O19](2-) was obtained; the bifunctionalized derivative of [Mo6O19](2-) was exclusively synthesized in the presence of non-protonated o-toluidine. The molecular and crystal structures of the hybrid compounds 1 and 2 were determined by X-ray single crystal diffraction, and their UV, IR and NMR spectra were compared. Additionally, a possible reaction mechanism was proposed.; Chemistry, Inorganic & Nuclear; SCI(E); 0; ARTICLE; 4; 773-779; 631
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/254217]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Li, Q,Wu, PF,Wei, YG,et al. Organic-inorganic hybrids: Preparation and structural characterization of (Bu4N)(2)]Mo6O17(NAr)(2)] and (Bu4N)(2)[Mo6O18(NAr)] (Ar = o-CH3C6H4)[J]. zeitschrift fur anorganische und allgemeine chemie,2005.
APA	Li, Q,Wu, PF,Wei, YG,Xia, Y,Wang, Y,&Guo, HY.(2005).Organic-inorganic hybrids: Preparation and structural characterization of (Bu4N)(2)]Mo6O17(NAr)(2)] and (Bu4N)(2)[Mo6O18(NAr)] (Ar = o-CH3C6H4).zeitschrift fur anorganische und allgemeine chemie.
MLA	Li, Q,et al."Organic-inorganic hybrids: Preparation and structural characterization of (Bu4N)(2)]Mo6O17(NAr)(2)] and (Bu4N)(2)[Mo6O18(NAr)] (Ar = o-CH3C6H4)".zeitschrift fur anorganische und allgemeine chemie (2005).