Tuning the magnetic behavior via dehydration/hydration treatment of a   new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)(6)center dot   6H(2)O

doi:10.1021/ic051145f

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	Tuning the magnetic behavior via dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O
	Lu, ZL ; Wang, XY ; Liu, ZL ; Liao, FH ; Gao, S ; Xiong, RG ; Ma, HW ; Zhang, DQ ; Zhu, DB
刊名	inorganic chemistry
	2006
关键词	PRUSSIAN BLUE ANALOGS BRIDGED BIMETALLIC COMPOUND COBALT-IRON CYANIDE CRYSTAL-STRUCTURE ORDERING TEMPERATURE MIXED-VALENCE T-C PHOTOINDUCED MAGNETIZATION 2-DIMENSIONAL FERRIMAGNET SPIN REORIENTATION
DOI	10.1021/ic051145f
英文摘要	A new complex (1) of Prussian blue analogue with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O was prepared and characterized structurally as well as magnetically. The crystal structure of complex 1 was determined by X-ray diffraction analysis. The results indicate that complex 1 consists of a 3D cubic lattice similar to those of Mn-3[Cr(CN)(6)](2)center dot xH(2)O, Mn-3[CO(CN)(6)](2)center dot xH(2)O, Cd-3[Cr(CN)(6)](2)center dot xH(2)O, and Cd-3[CO(CN)(6)](2)center dot xH(2)O, Magnetic measurements show that complex 1 is a ferrimagnet with T-c = 66 K. It is interesting to note that the magnetic behavior of complex 1 can be substantially modulated through a dehydration/rehydration treatment. The T-c value of this ferrimagnet increases to 99 K after dehydration reaching a 23.4% weight loss, and it decreases back to 66 K after the dehydrated sample reabsorbs water molecules.; Chemistry, Inorganic & Nuclear; SCI(E); 0; ARTICLE; 3; 999-1004; 45
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/252317]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Lu, ZL,Wang, XY,Liu, ZL,et al. Tuning the magnetic behavior via dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O[J]. inorganic chemistry,2006.
APA	Lu, ZL.,Wang, XY.,Liu, ZL.,Liao, FH.,Gao, S.,...&Zhu, DB.(2006).Tuning the magnetic behavior via dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O.inorganic chemistry.
MLA	Lu, ZL,et al."Tuning the magnetic behavior via dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)(6)center dot 6H(2)O".inorganic chemistry (2006).