Convenient syntheses and structural characterizations of   mono-substituted alkylimido hexamolybdates: [Mo6O18(NR)](2-) (R = Me,   Et, n-Pr, i-Pr, n-Bu, t-Bu, Cy, Hex, Ode)

doi:10.1039/b813924e

CORC > 北京大学 > 化学与分子工程学院

	Convenient syntheses and structural characterizations of mono-substituted alkylimido hexamolybdates: [Mo6O18(NR)](2-) (R = Me, Et, n-Pr, i-Pr, n-Bu, t-Bu, Cy, Hex, Ode)
	Li, Qiang ; Wang, Longsheng ; Yin, Panchao ; Wei, Yongge ; Hao, Jian ; Zhu, Yulin ; Zhu, Li ; Yuan, Gu
刊名	dalton transactions
	2009
关键词	DAWSON-TYPE POLYOXOTUNGSTATES MAIN-CHAIN-POLYOXOMETALATE ORGANIC-INORGANIC HYBRIDS ORGANOIMIDO DERIVATIVES OXOMOLYBDATE CLUSTERS MOLECULAR-STRUCTURE DIAZENIDO UNITS BUILDING-BLOCKS BOND FORMATION EFFICIENT
DOI	10.1039/b813924e
英文摘要	Monofunctionalized alkylimido derivatives of hexamolybdate, (Bu4N)(2)[Mo6O18( N-R)] (R = methyl, Me; ethyl, Et; n-propyl, n-Pr; i-propyl, i-Pr; n-butyl, n-Bu; t-butyl, t-Bu; cyclohexyl, Cy; n-hexyl, Hex; and n-octadecyl, Ode), have been prepared in high purity and good yield by the reaction of [Bu4N](4)[alpha-Mo8O26] with appropriate aliphatic amine hydrochlorides in anhydrous acetonitrile, using N,N'-dicyclohexylcarbodiimide (DCC) as the dehydrating agent. Eight compounds have been determined by single crystal X-ray diffraction analysis and all compounds have been studied with H-1-NMR, IR, UV-vis, ESI mass spectrometry and cyclic voltammetry. A structural and H-1-NMR study show beta hydrogen atoms of those alkylimido derivatives of hexamolybdate have strong Bronsted acidity compared to the hydrogen atoms in other positions.; Chemistry, Inorganic & Nuclear; SCI(E); EI; 7; ARTICLE; 7; 1172-1179
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/246657]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Li, Qiang,Wang, Longsheng,Yin, Panchao,et al. Convenient syntheses and structural characterizations of mono-substituted alkylimido hexamolybdates: [Mo6O18(NR)](2-) (R = Me, Et, n-Pr, i-Pr, n-Bu, t-Bu, Cy, Hex, Ode)[J]. dalton transactions,2009.
APA	Li, Qiang.,Wang, Longsheng.,Yin, Panchao.,Wei, Yongge.,Hao, Jian.,...&Yuan, Gu.(2009).Convenient syntheses and structural characterizations of mono-substituted alkylimido hexamolybdates: [Mo6O18(NR)](2-) (R = Me, Et, n-Pr, i-Pr, n-Bu, t-Bu, Cy, Hex, Ode).dalton transactions.
MLA	Li, Qiang,et al."Convenient syntheses and structural characterizations of mono-substituted alkylimido hexamolybdates: [Mo6O18(NR)](2-) (R = Me, Et, n-Pr, i-Pr, n-Bu, t-Bu, Cy, Hex, Ode)".dalton transactions (2009).