Synthesis of spinel LiMn2O4 with manganese carbonate prepared by micro-emulsion method | |
Ke, Du ; Rong, Hu Guo ; Dong, Peng Zhong ; Lu, Qi | |
刊名 | 电化学学报 |
2010 | |
关键词 | Lithium battery Spinel LiMn2O4 Micro-emulsion method High power LITHIUM-ION BATTERIES LOW-TEMPERATURE SYNTHESIS ELECTROCHEMICAL PROPERTIES CATHODE MATERIALS STRUCTURAL FATIGUE CAPACITY RETENTION EMULSION METHOD OXIDE SPINEL ONE-STEP CELLS |
DOI | 10.1016/j.electacta.2009.10.058 |
英文摘要 | Micro-spherical particle of MnCO3 has been successfully synthesized in CTAB-C8H18-C4H9OH-H2O micro-emulsion system. Mn2O3 decomposed from the MnCO3 is mixed with Li2CO3 and sintered at 800 degrees C for 12 h, and the pure spine! LiMn2O4 in sub-micrometer size is obtained. The LiMn2O4 has initial discharge specific capacity of 124 mAh g(-1) at discharge current of 120 mA g(-1) between 3 and 4.2V. and retains 118 mAh g-1 after 110 cycles. High-rate capability test shows that even at a current density of 16C. capacity about 103 mAh g(-1) is delivered, whose power is 57 times of that at 0.2C. The capacity loss rate at 55 degrees C is 0.27% per cycle. (C) 2009 Elsevier Ltd. All rights reserved.; Electrochemistry; SCI(E); EI; 6; ARTICLE; 5; 1733-1739; 55 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/245455] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Ke, Du,Rong, Hu Guo,Dong, Peng Zhong,et al. Synthesis of spinel LiMn2O4 with manganese carbonate prepared by micro-emulsion method[J]. 电化学学报,2010. |
APA | Ke, Du,Rong, Hu Guo,Dong, Peng Zhong,&Lu, Qi.(2010).Synthesis of spinel LiMn2O4 with manganese carbonate prepared by micro-emulsion method.电化学学报. |
MLA | Ke, Du,et al."Synthesis of spinel LiMn2O4 with manganese carbonate prepared by micro-emulsion method".电化学学报 (2010). |
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