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Synthesis of spinel LiMn2O4 with manganese carbonate prepared by micro-emulsion method
Ke, Du ; Rong, Hu Guo ; Dong, Peng Zhong ; Lu, Qi
刊名电化学学报
2010
关键词Lithium battery Spinel LiMn2O4 Micro-emulsion method High power LITHIUM-ION BATTERIES LOW-TEMPERATURE SYNTHESIS ELECTROCHEMICAL PROPERTIES CATHODE MATERIALS STRUCTURAL FATIGUE CAPACITY RETENTION EMULSION METHOD OXIDE SPINEL ONE-STEP CELLS
DOI10.1016/j.electacta.2009.10.058
英文摘要Micro-spherical particle of MnCO3 has been successfully synthesized in CTAB-C8H18-C4H9OH-H2O micro-emulsion system. Mn2O3 decomposed from the MnCO3 is mixed with Li2CO3 and sintered at 800 degrees C for 12 h, and the pure spine! LiMn2O4 in sub-micrometer size is obtained. The LiMn2O4 has initial discharge specific capacity of 124 mAh g(-1) at discharge current of 120 mA g(-1) between 3 and 4.2V. and retains 118 mAh g-1 after 110 cycles. High-rate capability test shows that even at a current density of 16C. capacity about 103 mAh g(-1) is delivered, whose power is 57 times of that at 0.2C. The capacity loss rate at 55 degrees C is 0.27% per cycle. (C) 2009 Elsevier Ltd. All rights reserved.; Electrochemistry; SCI(E); EI; 6; ARTICLE; 5; 1733-1739; 55
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/245455]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Ke, Du,Rong, Hu Guo,Dong, Peng Zhong,et al. Synthesis of spinel LiMn2O4 with manganese carbonate prepared by micro-emulsion method[J]. 电化学学报,2010.
APA Ke, Du,Rong, Hu Guo,Dong, Peng Zhong,&Lu, Qi.(2010).Synthesis of spinel LiMn2O4 with manganese carbonate prepared by micro-emulsion method.电化学学报.
MLA Ke, Du,et al."Synthesis of spinel LiMn2O4 with manganese carbonate prepared by micro-emulsion method".电化学学报 (2010).
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