Shape-Persistent Two-Component 2D Networks with Atomic-Size Tunability | |
Liu, Jia ; Zhang, Xu ; Wang, Dong ; Wang, Jie-Yu ; Pei, Jian ; Stang, Peter J. ; Wan, Li-Jun | |
刊名 | chemistry an asian journal
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2011 | |
关键词 | host-guest systems nanoporous network scanning tunnelling microscopy self-assembly LIQUID-SOLID INTERFACE SCANNING-TUNNELING-MICROSCOPY HOST-GUEST NETWORK NANOPOROUS NETWORKS SURFACE INCLUSION TEMPLATE ACID ORGANIZATION ASSEMBLIES |
DOI | 10.1002/asia.201100431 |
英文摘要 | Over the past few years, two-dimensional (2D) nanoporous networks have attracted great interest as templates for the precise localization and confinement of guest building blocks, such as functional molecules or clusters on the solid surfaces. Herein, a series of two-component molecular networks with a 3-fold symmetry are constructed on graphite using a truxenone derivative and trimesic acid homologues with carboxylic-acid-terminated alkyl chains. The hydrogen-bonding partner-recognition-induced 2D crystallization of alkyl chains makes the flexible alkyl chains act as rigid spacers in the networks to continuously tune the pore size with an accuracy of one carbon atom per step. The two-component networks were found to accommodate and regulate the distribution and aggregation of guest molecules, such as COR and CuPc. This procedure provides a new pathway for the design and fabrication of molecular nanostructures on solid surfaces.; Chemistry, Multidisciplinary; SCI(E); EI; 0; ARTICLE; 9; 2426-2430; 6 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/238056] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Liu, Jia,Zhang, Xu,Wang, Dong,et al. Shape-Persistent Two-Component 2D Networks with Atomic-Size Tunability[J]. chemistry an asian journal,2011. |
APA | Liu, Jia.,Zhang, Xu.,Wang, Dong.,Wang, Jie-Yu.,Pei, Jian.,...&Wan, Li-Jun.(2011).Shape-Persistent Two-Component 2D Networks with Atomic-Size Tunability.chemistry an asian journal. |
MLA | Liu, Jia,et al."Shape-Persistent Two-Component 2D Networks with Atomic-Size Tunability".chemistry an asian journal (2011). |
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