Stepwise tuning of the substituent groups from mother BTB ligands to two   hexaphenylbenzene based ligands for construction of diverse coordination   polymers

doi:10.1039/c3ce40856f

CORC > 北京大学 > 化学与分子工程学院

	Stepwise tuning of the substituent groups from mother BTB ligands to two hexaphenylbenzene based ligands for construction of diverse coordination polymers
	Wang, Lian-Cheng ; Sun, Junliang ; Huang, Zhi-Tang ; Zheng, Qi-Yu
刊名	crystengcomm
	2013
关键词	METAL-ORGANIC FRAMEWORKS SECONDARY BUILDING UNITS GAS-ADSORPTION PHOTOLUMINESCENT PROPERTIES SUPRAMOLECULAR ISOMERISM LUMINESCENT PROPERTIES THERMAL-STABILITY HYDROGEN UPTAKE NETWORKS MOLECULES
DOI	10.1039/c3ce40856f
英文摘要	Hexaphenylbenzene based tritopic carboxylate ligands H(3)L1 (1,3,5-tris(4-carboxyphenyl)-2,4,6-tris(4-tert-butylphenyl)benzene) and H(3)L2 (1,3,5-tris(4-carboxyphenyl)-2,4,6-triphenylbenzene) were applied to synthesize six coordination polymers (CPs) {[Zn-4(L1)(2)(mu(2)-OH)(2)(DMA)(4)(H2O)]center dot(C2H6O)(2)(H2O)}(n) (1), {[Cd-3(L1)(2)(mu(2)-H2O)(2)(H2O)(4)(DMF)(2)(C2H6O)]center dot(DMF) (H2O)(C2H6O)(2)}(n) (2), {[Cd(L1)(C2H6O)]center dot(H3O+)(DMF)(C2H6O)}(n) (3), {[Co-3(L1)(2)(mu(2)-H2O)(H2O)(6)(DMF)(2)(C2H6O)]center dot(DMF)(3)}(n) (4), {[Mn-3(L1)(2)(H2O)(5)(DMF)(4)(C2H6O)]center dot(C2H6O)}(n) (5), and {[Zn-2(L2)Cl(H2O)(DMA)]center dot(DMA)(2)(H2O)}(n) (6) (DMF = N, N-dimethylformamide, DMA = N, N-dimethylacetamide). The CPs were characterized by single crystal X-ray diffraction, infrared spectra (IR), elemental analyses, powder X-ray diffraction (PXRD), and thermogravimetric analyses (TGA). 1 and 2 exhibit two-dimensional (2D) honeycomb bilayer structures based on tetranuclear zinc or trinuclear cadmium clusters. 3 is PH-induced supramolecular isomer with 2, featuring 2D corrugated honeycomb structure. In 4 and 5, only two carboxylate groups coordinate with trinuclear metal clusters to form 1D coordination chains. The chains are further connected through hydrogen bonds between the left carboxylate groups and coordination water molecules to form honeycomb bilayer sheets. 6 exhibits 2D planar honeycomb structure based on Zn2(COO) 3 clusters. The different topological networks 1 and 6 are constructed from structurally similar ligands H3L1 and H3L2, showing that structural diversity could be realized by adjusting substituent groups on organic ligands. The photoluminescent behaviours of compounds 1, 2, and 6 and magnetic properties of 4 and 5 were also investigated.; Chemistry, Multidisciplinary; Crystallography; SCI(E); 2; ARTICLE; 42; 8511-8521; 15
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/227492]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Lian-Cheng,Sun, Junliang,Huang, Zhi-Tang,et al. Stepwise tuning of the substituent groups from mother BTB ligands to two hexaphenylbenzene based ligands for construction of diverse coordination polymers[J]. crystengcomm,2013.
APA	Wang, Lian-Cheng,Sun, Junliang,Huang, Zhi-Tang,&Zheng, Qi-Yu.(2013).Stepwise tuning of the substituent groups from mother BTB ligands to two hexaphenylbenzene based ligands for construction of diverse coordination polymers.crystengcomm.
MLA	Wang, Lian-Cheng,et al."Stepwise tuning of the substituent groups from mother BTB ligands to two hexaphenylbenzene based ligands for construction of diverse coordination polymers".crystengcomm (2013).