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Study of the diffusion behaviour of MoO3 and ZnO on oxide thin films by SR-TXRF
Xu, WM ; Xu, JQ ; Wu, NZ ; Yan, JF ; Zhu, YF ; Huang, YY ; He, W ; Xie, YC
2001
关键词MoO3 ZnO Al2O3 TiO2 SiO2 thin film SR-TXRF SUPPORTS
英文摘要The diffusion process Of MoO3 and ZnO on stable oxide thin films (SiO2, Al2O3, TiO2) was investigated mainly by means of synchrotron-radiation-excited total reflection x-ray fluorescence spectroscopy (SR-TXRF). A stripe Of MoO3 or ZnO on the oxide thin film was used as the diffusion source. After thermal treatment, MoO3 diffused onto the surface of those films and formed a monolayer or a submonolayer. The diffusion capacity and the diffusion rate Of MoO3 on each film differed significantly. Sublimation of MoO3 also was detected during the diffusion process. A possible explanation for all the phenomena is the combination of surface diffusion onto the surface of the support and transportation via the gas phase. By contrast, ZnO hardly diffuses onto the surface of the film due to its high melting point. Copyright (C) 2001 John Wiley & Sons, Ltd.; Chemistry, Physical; SCI(E); CPCI-S(ISTP); 3
语种英语
DOI标识10.1002/sia.1060
内容类型其他
源URL[http://ir.pku.edu.cn/handle/20.500.11897/206786]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Xu, WM,Xu, JQ,Wu, NZ,et al. Study of the diffusion behaviour of MoO3 and ZnO on oxide thin films by SR-TXRF. 2001-01-01.
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