Synthesis and characterization of a novel inorganic-organic hybrid   open-framework zinc phosphate with 16-ring channels

doi:10.1016/j.solidstatesciences.2014.11.007

CORC > 北京大学 > 化学与分子工程学院

	Synthesis and characterization of a novel inorganic-organic hybrid open-framework zinc phosphate with 16-ring channels
	Wang, Guo-Ming ; Li, Jin-Hua ; Gao, Cui-Li ; Zhang, Jun-Cheng ; Zhang, Xiao ; Bao, Zhen-Zhen ; Wang, Ying-Xia ; Lin, Jian-Hua
刊名	solid state sciences
	2015
关键词	Open framework Zinc phosphate 16-Ring channels Hybrid Luminescence PILLARED LAYERED STRUCTURE STATE NMR-SPECTROSCOPY CRYSTAL-STRUCTURE HYDROTHERMAL SYNTHESIS NETWORKS ULM-16
DOI	10.1016/j.solidstatesciences.2014.11.007
英文摘要	A novel inorganic-organic hybrid open-framework zinc phosphate, (NH4)[Zn-3(PO4)(3)(HPO4)(2)(HAPIM)(2)]center dot(H2O) (1), was solvothermally synthesized in the presence of 1-(3-aminopropyl)imidazole (APIM) as structure-directing agent. Its structure is built up by the alternate linkages between ZnO4, ZnO3N, PO4 and HPO4 tetrahedral moieties, forming an unusual three-dimensional framework with intersecting 8-, 10-, and 16-ring channels. The arrangement of the monoprotonated APIM molecules in 1 is unique and they play dual roles as both ligands and countercations. It is the first example with APIM as template in extra-large-channel structures in zincophosphates. The framework contains a Zn/P ratio of 1:1 and exhibits remarkable low framework density. Photoluminescence studies show that there is a ligand-to-metal charge transfer. (C) 2014 Published by Elsevier Masson SAS.; Chemistry, Inorganic & Nuclear; Chemistry, Physical; Physics, Condensed Matter; SCI(E); EI; 0; ARTICLE; gmwang_pub@163.com; 1-5; 39
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/206575]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Guo-Ming,Li, Jin-Hua,Gao, Cui-Li,et al. Synthesis and characterization of a novel inorganic-organic hybrid open-framework zinc phosphate with 16-ring channels[J]. solid state sciences,2015.
APA	Wang, Guo-Ming.,Li, Jin-Hua.,Gao, Cui-Li.,Zhang, Jun-Cheng.,Zhang, Xiao.,...&Lin, Jian-Hua.(2015).Synthesis and characterization of a novel inorganic-organic hybrid open-framework zinc phosphate with 16-ring channels.solid state sciences.
MLA	Wang, Guo-Ming,et al."Synthesis and characterization of a novel inorganic-organic hybrid open-framework zinc phosphate with 16-ring channels".solid state sciences (2015).