Iodo-controlled selective formation of pyrrolidino[60]fullerene and   aziridino[60]fullerene from the reaction between C-60 and amino acid   esters

doi:10.1021/jo0493368

CORC > 北京大学 > 化学与分子工程学院

	Iodo-controlled selective formation of pyrrolidino[60]fullerene and aziridino[60]fullerene from the reaction between C-60 and amino acid esters
	Zhang, X ; Gan, LB ; Huang, SH ; Shi, YR
刊名	journal of organic chemistry
	2004
关键词	POLYVALENT IODINE COMPOUNDS FULLERENE DERIVATIVES < FUNCTIONALIZATION CHEMISTRY 60> FULLERENE
DOI	10.1021/jo0493368
英文摘要	The reaction between glycine methyl ester and C-60 can be effectively controlled by different iodo-reagents. Addition of DIB ((diacetoxyiodo)benzene) yields the 2,5-bismethoxycarbonyl pyrrolidino[60]fullerene under ultrasonic irradiation; whereas addition of DIB-iodine results in the N-methoxycarbonylmethyl aziridino [60] fullerene under ultrasonic irradiation. The reaction of sarcosine methyl ester with C-60 is similar to that of glycine methyl ester under these two conditions. Addition of just iodine to a mixture of sarcosine methyl ester and C-60 affords the tetra(amino) [60] fullerene epoxide C-60(O)((Me)NCH2COOMe)(4). Possible mechanisms are discussed.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000223278200046&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Organic; SCI(E); EI; PubMed; 33; ARTICLE; 17; 5800-5802; 69
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/200274]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, X,Gan, LB,Huang, SH,et al. Iodo-controlled selective formation of pyrrolidino[60]fullerene and aziridino[60]fullerene from the reaction between C-60 and amino acid esters[J]. journal of organic chemistry,2004.
APA	Zhang, X,Gan, LB,Huang, SH,&Shi, YR.(2004).Iodo-controlled selective formation of pyrrolidino[60]fullerene and aziridino[60]fullerene from the reaction between C-60 and amino acid esters.journal of organic chemistry.
MLA	Zhang, X,et al."Iodo-controlled selective formation of pyrrolidino[60]fullerene and aziridino[60]fullerene from the reaction between C-60 and amino acid esters".journal of organic chemistry (2004).