Preparation of [5,6]- and [6,6]-oxahomofullerene derivatives and their   interconversion by lewis acid assisted reactions of fullerene mixed   peroxides

doi:10.1002/chem.200500393

CORC > 北京大学 > 化学与分子工程学院

	Preparation of [5,6]- and [6,6]-oxahomofullerene derivatives and their interconversion by lewis acid assisted reactions of fullerene mixed peroxides
	Huang, SH ; Xiao, Z ; Wang, FD ; Zhou, J ; Yuan, G ; Zhang, SW ; Chen, ZF ; Thiel, W ; Schleyer, PV ; Zhang, X ; Hu, XQ ; Chen, BC ; Gan, LB
刊名	chemistry a european journal
	2005
关键词	epoxides fullerenes hemiketals isomenzation peroxides C-13 NMR-SPECTRA DENSITY-FUNCTIONAL THEORY IPR ISOMERS C-60 C-70 FULLEROIDS CAGE OXAHOMOFULLERENE IDENTIFICATION HOMOFULLERENE
DOI	10.1002/chem.200500393
英文摘要	[60]Fullerene mixed peroxides C-60(O)(OOtBu)(4) exhibit chemoand regioselective reactions under mild conditions. The epoxy moiety is opened by ferric chloride to form vicinal hydroxy chloride C60Cl(OH)(OOtBu)-BF3 is also effective in opening the epoxy moiety. The O-O bond of the fullerene mixed peroxide is cleaved by both [5,6]- and type aluminum chloride to form and [6,6]-fullerene hemiketals (oxohomo[60]fullerenes). A Hocktype rearrangement is proposed for the formation of the hemiketals, in which a fullerene C-C bond is cleaved. Lewis acids and/or visible light can initiate isomerization of the hemiketal isomers. Single-crystal X-ray analysis and theoretical calculations confirmed the results.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000231771700029&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 36; ARTICLE; 18; 5449-5456; 11
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/199292]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Huang, SH,Xiao, Z,Wang, FD,et al. Preparation of [5,6]- and [6,6]-oxahomofullerene derivatives and their interconversion by lewis acid assisted reactions of fullerene mixed peroxides[J]. chemistry a european journal,2005.
APA	Huang, SH.,Xiao, Z.,Wang, FD.,Zhou, J.,Yuan, G.,...&Gan, LB.(2005).Preparation of [5,6]- and [6,6]-oxahomofullerene derivatives and their interconversion by lewis acid assisted reactions of fullerene mixed peroxides.chemistry a european journal.
MLA	Huang, SH,et al."Preparation of [5,6]- and [6,6]-oxahomofullerene derivatives and their interconversion by lewis acid assisted reactions of fullerene mixed peroxides".chemistry a european journal (2005).