Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with   N-Tosylhydrazones or Diazoesters through C-H Activation

doi:10.1002/anie.201309650

CORC > 北京大学 > 化学与分子工程学院

	Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation
	Hu, Fangdong ; Xia, Ying ; Ye, Fei ; Liu, Zhenxing ; Ma, Chen ; Zhang, Yan ; Wang, Jianbo
刊名	angewandte chemie international edition
	2014
关键词	C-H activation diazo compounds homogeneous catalysis metal-carbene complexes migratory insertion DIAZO-COMPOUNDS BOND FORMATION DIRHODIUM(II) CARBOXYLATES INSERTION REACTIONS DIRECTING GROUP ALKYNES FUNCTIONALIZATION CONSTRUCTION REACTIVITIES ISOCYANATES
DOI	10.1002/anie.201309650
英文摘要	A coupling reaction of N-phenoxyacetamides with N-tosylhydrazones or diazoesters through Rh-III-catalyzed C-H activation is reported. In this reaction, ortho-alkenyl phenols were obtained in good yields and with excellent regio- and stereoselectivity. Rh-carbene migratory insertion is proposed as the key step in the reaction mechanism.; Chemistry, Multidisciplinary; SCI(E); PubMed; 30; ARTICLE; wangjb@pku.edu.cn; 5; 1364-1367; 53
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/190082]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Hu, Fangdong,Xia, Ying,Ye, Fei,et al. Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation[J]. angewandte chemie international edition,2014.
APA	Hu, Fangdong.,Xia, Ying.,Ye, Fei.,Liu, Zhenxing.,Ma, Chen.,...&Wang, Jianbo.(2014).Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation.angewandte chemie international edition.
MLA	Hu, Fangdong,et al."Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation".angewandte chemie international edition (2014).