New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal   framework: Synthesis, structure and coordination modes

doi:10.1016/j.molstruc.2009.08.009

CORC > 北京大学 > 化学与分子工程学院

	New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes
	Su, Jie ; Wang, Yingxia ; Li, Weihong ; Yang, Sihai ; Li, Guobao ; Liao, Fuhui ; Lin, Jianhua
刊名	分子结构杂志
	2009
关键词	Gallium formate Indium formate Sodium formate Double formates X-ray crystal structure CRYSTAL-STRUCTURE THERMAL-DECOMPOSITION WEAK FERROMAGNETISM NEUTRON-DIFFRACTION MANGANESE FORMATE IRON(II) FORMATE RAMAN-SCATTERING SINGLE-CRYSTALS CO NI
DOI	10.1016/j.molstruc.2009.08.009
英文摘要	Two new double formates, Na3M(HCOO)(6) (M = Ga, In), have been synthesized by using quasi-solvothermal method. Both Compounds are iscistructural, crystallizing in orthorhombic space group Pccn, with lattice parameters a = 14.6279(5) angstrom, b = 6.2607(1) angstrom, and c = 13.5132(4) angstrom for Na3Ga(HCOO)(6) and a = 14.6054(5) angstrom, b = 6.4160(1) angstrom, and c = 13.9444(3) angstrom for Na3In(HCOO)(6). The structure takes a three-dimensional framework consisting of MO6 and NaO6 octahedra which are connected in edge- and corner-sharing modes. Regarding to the linkage of octahedra, the framework could be considered as a diamond net. The formates in the structure bridge the metal octahedra in an unusual 4.22 connection mode. IR spectroscopy and elemental analysis support the Structure characterization. Thermal decomposition process was also studied by TG and X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.; Chemistry, Physical; SCI(E); 1; ARTICLE; 1-3; 39-43; 937
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/151242]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Su, Jie,Wang, Yingxia,Li, Weihong,et al. New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes[J]. 分子结构杂志,2009.
APA	Su, Jie.,Wang, Yingxia.,Li, Weihong.,Yang, Sihai.,Li, Guobao.,...&Lin, Jianhua.(2009).New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes.分子结构杂志.
MLA	Su, Jie,et al."New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes".分子结构杂志 (2009).