Syntheses, Structures, and Structural Transformations of Mixed Na(I) and   Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands

doi:10.1021/cg101610k

CORC > 北京大学 > 化学与分子工程学院

	Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands
	Fu, Ying ; Su, Jie ; Yang, Sihai ; Zou, Zhibo ; Li, Guobao ; Liao, Fuhui ; Xiong, Ming ; Lin, Jianhua
刊名	crystal growth design
	2011
关键词	POROUS COORDINATION-POLYMER SINGLE-CRYSTAL TRANSFORMATIONS SOLID-STATE SORPTION PROPERTIES SPIN-CROSSOVER HYDROGEN-BOND BEHAVIOR MOLECULES NETWORK ACID
DOI	10.1021/cg101610k
英文摘要	Three new compounds, [ZnNa(BTC)(H2O)(2)]center dot H2O (1), [Zn3Na2(BTC)(2)(HCOO)(2)(H2O)(8)] (2), and [Zn3Na(BTC)(2) (HCOO)(H2O)3]center dot H2O (3) (H3BTC = 1,3,5-benzenetricarboxylate acid), were synthesized under hydrothermal conditions and were characterized by the single crystal and powder X-ray diffraction, IR spectra, elemental analyses, ICP measurements, and coupled TG-MS analyses. 1, 2, and 3 crystallize in the space groups P (1) over bar, C2/c, and P1, respectively. They are three-dimensional (3D) frameworks, consisting of zigzag chains ((Na2Zn2O14)(n) for 1, (Na2Zn3O18)(n) for 2, or (NaZn3O14)(n) for 3) and bridging BTC ligands. Powder X-ray diffraction studies reveal that 1 and 2 exhibit reversible dehydration-rehydration behaviors with a crystal-to-crystal transformation observed for 2.; Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary; SCI(E); 9; ARTICLE; 6; 2243-2249; 11
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/151039]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Fu, Ying,Su, Jie,Yang, Sihai,et al. Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands[J]. crystal growth design,2011.
APA	Fu, Ying.,Su, Jie.,Yang, Sihai.,Zou, Zhibo.,Li, Guobao.,...&Lin, Jianhua.(2011).Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands.crystal growth design.
MLA	Fu, Ying,et al."Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands".crystal growth design (2011).