Applications of homochiral metal-organic frameworks in enantioselective adsorption and chromatography separation | |
Li, Xianjiang ; Chang, Cuilan ; Wang, Xin ; Bai, Yu ; Liu, Huwei | |
刊名 | electrophoresis |
2014 | |
关键词 | Chiral separation Chiral stationary phase Enantioselective adsorption Metal-organic frameworks PERFORMANCE LIQUID-CHROMATOGRAPHY HIGHLY SELECTIVE SEPARATION INTRINSIC CHIRAL TOPOLOGY ACHIRAL BUILDING-BLOCKS STATIONARY-PHASE COORDINATION POLYMERS CAPILLARY ELECTROCHROMATOGRAPHY ABSOLUTE HELICITY POROUS SOLIDS RESOLUTION |
DOI | 10.1002/elps.201400079 |
英文摘要 | Chiral separation is of great importance for drug development, pharmacology, and biology. Chiral metal-organic frameworks (MOFs) is a new class of porous solid materials with high surface area, large pore size, high chemical stability, uniformly structured cavities, and the availability of modification. The excellent properties of MOFs have attracted intense interest to explore their performance and mechanism in chiral separation. This review summarizes three synthetic strategies of chiral MOFs and their applications in enantioselective adsorption and chromatographic separation. All the experimental and molecular simulation results demonstrated that high enantioselectivity was strongly correlated with a close match between the size of the pore and chiral molecules.; Biochemical Research Methods; Chemistry, Analytical; SCI(E); 6; REVIEW; hwliu@pku.edu.cn; 19,SI; 2733-2743; 35 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/150382] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Li, Xianjiang,Chang, Cuilan,Wang, Xin,et al. Applications of homochiral metal-organic frameworks in enantioselective adsorption and chromatography separation[J]. electrophoresis,2014. |
APA | Li, Xianjiang,Chang, Cuilan,Wang, Xin,Bai, Yu,&Liu, Huwei.(2014).Applications of homochiral metal-organic frameworks in enantioselective adsorption and chromatography separation.electrophoresis. |
MLA | Li, Xianjiang,et al."Applications of homochiral metal-organic frameworks in enantioselective adsorption and chromatography separation".electrophoresis (2014). |
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