Peroxide-Mediated Selective Cleavage of [60]Fullerene Skeleton Bonds:   Towards the Synthesis of Open-Cage Fulleroid C55O5

doi:10.1002/tcr.201402057

CORC > 北京大学 > 化学与分子工程学院

	Peroxide-Mediated Selective Cleavage of [60]Fullerene Skeleton Bonds: Towards the Synthesis of Open-Cage Fulleroid C55O5
	Gan, Liangbing
刊名	chemical record
	2015
关键词	cage compounds fullerenes molecular containers peroxides radical reactions ISOMERICALLY PURE FULLERENOLS X-RAY STRUCTURES MOLECULAR-HYDROGEN MIXED PEROXIDES VICINAL FULLERENDIOL MILD CONDITIONS SINGLET OXYGEN CARBON-ATOM C-60 DERIVATIVES
DOI	10.1002/tcr.201402057
英文摘要	Replacement of a pentagon in [60]fullerene with five oxygen atoms yields the open-cage compound C55O5 with five carbonyl groups on the rim of the orifice. Our attempts to synthesize such a target molecule starting from C-60 have led us to prepare the fullerene-mixed peroxides such as C-60(OO-t-Bu)(6) with all the peroxo addends surrounding the same pentagon. Further investigations of the peroxide chemistry have generated various open-cage fullerene derivatives, including the carbon monoxide encapsulated endohedral compound CO@C59O6. This Personal Account mainly discusses peroxide-based processes resulting in selective cleavage of the fullerene skeleton bonds.; Chemistry, Multidisciplinary; SCI(E); 2; ARTICLE; gan@pku.edu.cn; 1,SI; 189-198; 15
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/150326]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Gan, Liangbing. Peroxide-Mediated Selective Cleavage of [60]Fullerene Skeleton Bonds: Towards the Synthesis of Open-Cage Fulleroid C55O5[J]. chemical record,2015.
APA	Gan, Liangbing.(2015).Peroxide-Mediated Selective Cleavage of [60]Fullerene Skeleton Bonds: Towards the Synthesis of Open-Cage Fulleroid C55O5.chemical record.
MLA	Gan, Liangbing."Peroxide-Mediated Selective Cleavage of [60]Fullerene Skeleton Bonds: Towards the Synthesis of Open-Cage Fulleroid C55O5".chemical record (2015).