Towards the rational synthesis of norfullerenes. Controlled deletion of   one carbon atom from C(60) and preparation of   2,5,9-trioxo-1-nor(C(60)-I(h))[5,6]fullerene C(59)(O)(3) derivatives

doi:10.1021/ol800611r

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	Towards the rational synthesis of norfullerenes. Controlled deletion of one carbon atom from C(60) and preparation of 2,5,9-trioxo-1-nor(C(60)-I(h))[5,6]fullerene C(59)(O)(3) derivatives
	Yao, Jiayao ; Xiao, Zuo ; Gan, Liangbing ; Yang, Dazhi ; Wang, Zheming
刊名	organic letters
	2008
关键词	CAGE FULLERENE DERIVATIVES MOLECULAR-HYDROGEN MIXED PEROXIDES GAS-PHASE ORIFICE RING INTERCONVERSION FRAGMENTATION ENCAPSULATION SPECTROSCOPY
DOI	10.1021/ol800611r
英文摘要	Norfullerenes are fullerene-like compounds (fulleroids) resulting from partial deletion of fullerene skeleton carbons. The one carbon less norfullerene C(59)(O)(3) derivatives having three carbonyl groups on the rim of the orifice are prepared through peroxide-mediated reactions. A key step involves a novel PCI(5) initiated rearrangement of a hydroxyl amine adduct. Decarboxylation serves as the carbon removal step.; Chemistry, Organic; SCI(E); PubMed; 9; ARTICLE; 10; 2003-2006; 10
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/150236]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yao, Jiayao,Xiao, Zuo,Gan, Liangbing,et al. Towards the rational synthesis of norfullerenes. Controlled deletion of one carbon atom from C(60) and preparation of 2,5,9-trioxo-1-nor(C(60)-I(h))[5,6]fullerene C(59)(O)(3) derivatives[J]. organic letters,2008.
APA	Yao, Jiayao,Xiao, Zuo,Gan, Liangbing,Yang, Dazhi,&Wang, Zheming.(2008).Towards the rational synthesis of norfullerenes. Controlled deletion of one carbon atom from C(60) and preparation of 2,5,9-trioxo-1-nor(C(60)-I(h))[5,6]fullerene C(59)(O)(3) derivatives.organic letters.
MLA	Yao, Jiayao,et al."Towards the rational synthesis of norfullerenes. Controlled deletion of one carbon atom from C(60) and preparation of 2,5,9-trioxo-1-nor(C(60)-I(h))[5,6]fullerene C(59)(O)(3) derivatives".organic letters (2008).