Synthesis of Fullerene Oxides Containing Both 6,6-Closed Epoxide and   5,6-Open Ether Moieties through Thermolysis of Fullerene Peroxides

doi:10.1021/jo9000977

CORC > 北京大学 > 化学与分子工程学院

	Synthesis of Fullerene Oxides Containing Both 6,6-Closed Epoxide and 5,6-Open Ether Moieties through Thermolysis of Fullerene Peroxides
	Yao, Jiayao ; Yang, Dazhi ; Xiao, Zuo ; Gan, Liangbing ; Wang, Zheming
刊名	journal of organic chemistry
	2009
关键词	X-RAY STRUCTURES MIXED PEROXIDES C-60 OXIDATION C-70 DERIVATIVES BUCKMINSTERFULLERENE OZONIDES ADDUCTS ISOMER
DOI	10.1021/jo9000977
英文摘要	Thermolysis of the fullerene hexaadduct C(60)(OO'Bu)(6) results in cleavage of two O-O bonds and elimination of two tert-butoxy groups to form two isomeric products with the formula C(60)(O)(2)(OO'Bu)(4) in comparable yields. The two oxygen atoms exist as two epoxy groups in one isomer 3, and as an epoxy and an ether group in the other isomer 2. Addition of hydroxylamine to 2 opens both the epoxy and the ether moieties to give a cage-opened keto-ketoxime derivative.; Chemistry, Organic; SCI(E); EI; PubMed; 9; ARTICLE; 9; 3528-3531; 74
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/150176]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yao, Jiayao,Yang, Dazhi,Xiao, Zuo,et al. Synthesis of Fullerene Oxides Containing Both 6,6-Closed Epoxide and 5,6-Open Ether Moieties through Thermolysis of Fullerene Peroxides[J]. journal of organic chemistry,2009.
APA	Yao, Jiayao,Yang, Dazhi,Xiao, Zuo,Gan, Liangbing,&Wang, Zheming.(2009).Synthesis of Fullerene Oxides Containing Both 6,6-Closed Epoxide and 5,6-Open Ether Moieties through Thermolysis of Fullerene Peroxides.journal of organic chemistry.
MLA	Yao, Jiayao,et al."Synthesis of Fullerene Oxides Containing Both 6,6-Closed Epoxide and 5,6-Open Ether Moieties through Thermolysis of Fullerene Peroxides".journal of organic chemistry (2009).