An Experimentally Observed Trimetallofullerene Sm-3@I-h-C-80:   Encapsulation of Three Metal Atoms in a Cage without a Nonmetallic   Mediator

doi:10.1021/ja400490u

CORC > 北京大学 > 化学与分子工程学院

	An Experimentally Observed Trimetallofullerene Sm-3@I-h-C-80: Encapsulation of Three Metal Atoms in a Cage without a Nonmetallic Mediator
	Xu, Wei ; Feng, Lai ; Calvaresi, Matteo ; Liu, Jia ; Liu, Yang ; Niu, Ben ; Shi, Zujin ; Lian, Yongfu ; Zerbetto, Francesco
刊名	journal of the american chemical society
	2013
关键词	CARBIDE ENDOHEDRAL METALLOFULLERENE ISOLATED PENTAGON RULE FULLERENE CAGE STRUCTURAL-CHARACTERIZATION CLUSTER LA-2-AT-C-80 FUNCTIONALIZATION SC2C2-AT-C-82 ELUCIDATION SEPARATION
DOI	10.1021/ja400490u
英文摘要	We report the synthesis, isolation, and characterizations of the novel trimetallofullerene Sm-3@I-h-C-80. Importantly, the experimental X-ray structure of Sm-3@I-h-C-80 verified for the first time that three metal atoms can be stabilized in a fullerene cage without a nonmetal mediator. Furthermore, computational studies demonstrated the electronic features of Sm-3@I-h-C-80, which are similar to that of theoretically studied Y-3@I-h-C-80. Electrochemical studies of Sm-3@I-h-C-80 showed a major difference from those of the well-studied isoelectronic species Sc3N@I-h-C-80 and La-2@I-h-C-80.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000316774100007&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 22; ARTICLE; 11; 4187-4190; 135
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/149813]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xu, Wei,Feng, Lai,Calvaresi, Matteo,et al. An Experimentally Observed Trimetallofullerene Sm-3@I-h-C-80: Encapsulation of Three Metal Atoms in a Cage without a Nonmetallic Mediator[J]. journal of the american chemical society,2013.
APA	Xu, Wei.,Feng, Lai.,Calvaresi, Matteo.,Liu, Jia.,Liu, Yang.,...&Zerbetto, Francesco.(2013).An Experimentally Observed Trimetallofullerene Sm-3@I-h-C-80: Encapsulation of Three Metal Atoms in a Cage without a Nonmetallic Mediator.journal of the american chemical society.
MLA	Xu, Wei,et al."An Experimentally Observed Trimetallofullerene Sm-3@I-h-C-80: Encapsulation of Three Metal Atoms in a Cage without a Nonmetallic Mediator".journal of the american chemical society (2013).